1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile

Base Information

• Chemical Name: 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile
• CAS No.: 1417815-78-1
• Molecular Formula: C₂₈H₂₈N₄O₄S₄
• Molecular Weight: 612.819
• Mol file: 1417815-78-1.mol

Synonyms:1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile

Chemical Property of 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile

There total 1 articles about 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

N,N'-(2,2'-(ethane-1,2-diylbis(sulfanediyl))bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide) (908824-06-6) + 4,5-dichlorophthalonitrile (139152-08-2) → 1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile (1417815-78-1)

Guidance literature:

N,N'-(2,2'-(ethane-1,2-diylbis(sulfanediyl))bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide); With potassium carbonate; In acetonitrile; at 50 ℃; for 2h; Inert atmosphere; Schlenk technique;

4,5-dichlorophthalonitrile; In acetonitrile; for 144h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.3184/174751912X13472922835683

Reference yield: 33.0%

1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile (1417815-78-1) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → C112H112CoN16O16S16

Guidance literature:

at 175 ℃; for 0.166667h; Microwave irradiation; Inert atmosphere; Schlenk technique;

DOI:10.3184/174751912X13472922835683

Reference yield: 31.0%

1,10-ditosyl-1,2,3,5,6,8,9,10-octahydrobenzo[h][1,4,7,10]dithiadiazacyclododecine-12,13-dicarbonitrile (1417815-78-1) + zinc diacetate (557-34-6) → C112H112N16O16S16Zn

Guidance literature:

at 175 ℃; for 0.166667h; Microwave irradiation; Inert atmosphere; Schlenk technique;

DOI:10.3184/174751912X13472922835683

upstream raw materials:

N,N'-(2,2'-(ethane-1,2-diylbis(sulfanediyl))bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide)

4,5-dichlorophthalonitrile