C₃₇H₅₃NO₁₀Si

Base Information

• Chemical Name: C₃₇H₅₃NO₁₀Si
• CAS No.: 175441-57-3
• Molecular Formula: C₃₇H₅₃NO₁₀Si
• Molecular Weight: 699.914
• Mol file: 175441-57-3.mol

Synonyms:C₃₇H₅₃NO₁₀Si

Chemical Property of C₃₇H₅₃NO₁₀Si

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of C₃₇H₅₃NO₁₀Si

There total 5 articles about C₃₇H₅₃NO₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

C37H51N3O10Si (175441-56-2) → C37H53NO10Si (175441-57-3)

Guidance literature:

With Benzeneselenol; triethylamine; at 60 ℃; for 3h;

DOI:10.1021/jo952067o

Reference yield:

7-(triethylsilyl)baccatin III (115437-21-3) → C37H53NO10Si (175441-57-3)

Guidance literature:

Multi-step reaction with 5 steps

1: 1.) imidazole, 2.) imidazole / 1.) DMF, 0 deg C, 1.5 h, 2.) 0 deg C, 1 h

2: 58 percent / Red-Al / tetrahydrofuran / 0.67 h / 0 °C

3: 1.) triphenylphosphine, carbon tetrachloride, 2.) NaN₃ / 1.) dichloromethane, 0 deg C, 1 h, 2.) DMF, 40 deg C, 2 h

4: 22 percent / DMAP / toluene / 13 h / 80 °C

5: 58 percent / PhSeH, triethylamine / 3 h / 60 °C

With 1H-imidazole; tetrachloromethane; dmap; sodium azide; Benzeneselenol; triethylamine; triphenylphosphine; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; toluene;

DOI:10.1021/jo952067o

Reference yield:

4-deacetyl-1-dimethylsilyl-7-triethylsilylbaccatin III (175441-49-3) → C37H53NO10Si (175441-57-3)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) triphenylphosphine, carbon tetrachloride, 2.) NaN₃ / 1.) dichloromethane, 0 deg C, 1 h, 2.) DMF, 40 deg C, 2 h

2: 22 percent / DMAP / toluene / 13 h / 80 °C

3: 58 percent / PhSeH, triethylamine / 3 h / 60 °C

With tetrachloromethane; dmap; sodium azide; Benzeneselenol; triethylamine; triphenylphosphine; In toluene;

DOI:10.1021/jo952067o

upstream raw materials:

C₃₇H₅₁N₃O₁₀Si

7-(triethylsilyl)baccatin III

4-deacetyl-1-dimethylsilyl-7-triethylsilylbaccatin III

C₄₂H₆₆O₁₁Si₃