2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

Base Information

Chemical Name:2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate
CAS No.:1132966-47-2
Molecular Formula:C₁₉H₂₃N₃O₉
Molecular Weight:437.406
Hs Code.:

Synonyms:2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

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Technology Process of 2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

There total 5 articles about 2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 84278-00-2
1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-D-galactopyranose

: 150-76-5
4-methoxy-phenol

: 1132966-47-2
2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 15 ℃; for 3h;
DOI:10.1016/j.tetasy.2008.12.006

Reference yield:

: 68733-19-7
3,4,6-tri-O-acetyl-2-azido-2-deoxy-β-D-galactopyranosyl acetate

: 150-76-5
4-methoxy-phenol

: 1132966-47-2
2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

: 1139852-98-4
2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

Guidance literature:: 3,4,6-tri-O-acetyl-2-azido-2-deoxy-β-D-galactopyranosyl acetate; 4-methoxy-phenol; With boron trifluoride diethyl etherate; In dichloromethane; at 0 - 20 ℃; for 72h;

With hydrazinium monoacetate; In N,N-dimethyl-formamide; at 20 ℃; for 1.5h; Overall yield = 86 %; Overall yield = 5.91 g;
DOI:10.1016/j.tet.2016.07.042

Reference yield:

: 84278-00-2
1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-D-galactopyranose

: 150-76-5
4-methoxy-phenol

: 1132966-47-2
2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

: 1139852-98-4
2-(acetoxymethyl)-5-azido-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4-diyl diacetate

Guidance literature:: With trifluorormethanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 17h; Overall yield = 2.3 g; Inert atmosphere;
DOI:10.1039/c9ob00057g