benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester

Base Information

Chemical Name:benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester
CAS No.:96150-74-2
Molecular Formula:C₁₉H₂₄O₆
Molecular Weight:348.396
Hs Code.:

Synonyms:benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester

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Chemical Property of benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester

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Technology Process of benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester

There total 3 articles about benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 504-61-0,542-72-3
(E)-but-2-enol

: 96150-86-6
benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid chloride

: 96150-74-2
benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester

Guidance literature:: With dmap; In dichloromethane; at 0 ℃;
DOI:10.1021/ja00297a038

Reference yield:

: 74912-02-0,79940-48-0,94118-99-7,20689-03-6
1-O-benzyl-2,3-O-isopropylidene-α-D-manno-furanose

: 96150-74-2
benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaIO₄; 2.) AgNO₃, KOH (85percent) / 1.) MeOH, H₂O, 1 h 75 min; 2.) H₂O, EtOH, 9.5 h

2: 4.10 g / (COCl)2, DMF / benzene / 2 h / Ambient temperature

3: 98 percent / DMAP / CH₂Cl₂ / 0 °C

With dmap; potassium hydroxide; sodium periodate; oxalyl dichloride; silver nitrate; N,N-dimethyl-formamide; In dichloromethane; benzene;
DOI:10.1021/ja00297a038

Reference yield:

: 96150-84-4
(3aR,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole-4-carboxylic acid

: 96150-74-2
benzyl 2,3-O-(1-methylethylidene)-α-D-lyxofuranosiduronic acid, trans-crotyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 4.10 g / (COCl)2, DMF / benzene / 2 h / Ambient temperature

2: 98 percent / DMAP / CH₂Cl₂ / 0 °C

With dmap; oxalyl dichloride; N,N-dimethyl-formamide; In dichloromethane; benzene;
DOI:10.1021/ja00297a038