(S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Base Information

• Chemical Name: (S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
• CAS No.: 243979-20-6
• Molecular Formula: C₂₇H₄₂O₂Si
• Molecular Weight: 426.715
• Mol file: 243979-20-6.mol

Synonyms:(S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Chemical Property of (S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

There total 1 articles about (S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(3,3-dimethyl-but-1-ynyl)benzene (4250-82-2) + L-menthyl (trimethylsilyl)diazoacetate → (R)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester + (S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester (243979-20-6)

Guidance literature:

UV-irradiation;

DOI:10.1021/ja991224o

Reference yield:

(S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester (243979-20-6) → 2-tert-Butyl-3-phenyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Guidance literature:

With tetrabutyl ammonium fluoride; benzaldehyde; In tetrahydrofuran; at 65 ℃;

DOI:10.1021/ja991224o

Reference yield:

benzaldehyde (100-52-7) + (S)-2-tert-Butyl-3-phenyl-1-trimethylsilanyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester (243979-20-6) → 2-tert-Butyl-3-phenyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester + 2-tert-Butyl-1-(hydroxy-phenyl-methyl)-3-phenyl-cycloprop-2-enecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 65 ℃;

DOI:10.1021/ja991224o

upstream raw materials:

(3,3-dimethyl-but-1-ynyl)benzene