(tris[2-(diphenylphsophino)ethyl]amino)CoH

Base Information

• Chemical Name: (tris[2-(diphenylphsophino)ethyl]amino)CoH
• CAS No.: 53687-39-1
• Molecular Formula: C₄₂H₄₃CoNP₃
• Molecular Weight: 713.725
• Mol file: 53687-39-1.mol

Synonyms:(tris[2-(diphenylphsophino)ethyl]amino)CoH

Chemical Property of (tris[2-(diphenylphsophino)ethyl]amino)CoH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (tris[2-(diphenylphsophino)ethyl]amino)CoH

There total 3 articles about (tris[2-(diphenylphsophino)ethyl]amino)CoH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[tris(2-(diphenylphosphino)ethyl)amine]Co(COCH3) (97149-88-7) + lithium triethylborohydride (22560-16-3) → {(N(CH2CH2P(C6H5)2)3)CoH} (53687-39-1,97135-32-5)

Guidance literature:

In tetrahydrofuran; THF suspn. of Co complex treated with LiHBEt3 (1 M in THF) at 0°C; butanol added, crystals filtered, washed with EtOH and petroleum ether;

DOI:10.1021/om00128a009

Reference yield: 50.0%

[tris(2-(diphenylphosphino)ethyl)amine]Co(COCH3) (97149-88-7) + sodium tetraphenyl borate (143-66-8) → {(N(CH2CH2P(C6H5)2)3)CoH} (53687-39-1,97135-32-5) + [(tris(2-(diphenylphosphino)ethyl)amine)Co(CO)]BPh4 (97135-37-0)

Guidance literature:

With sodium methoxide; In tetrahydrofuran; methanol; 1 M soln. of MeONa in MeOH added to suspn. of educt in THF, stirred for2 d; addn. of butanol, sepn. of crystals, addn. of NaBPh4 to mother liquor;

DOI:10.1021/om00128a009

Reference yield:

sodium tetrahydroborate (16940-66-2) + cobalt(II) tetrafluoroborate hexahydrate (15684-35-2) + tris(2-(diphenylphosphino)ethyl)amine (15114-55-3) → {(N(CH2CH2P(C6H5)2)3)CoH} (53687-39-1,97135-32-5)

Guidance literature:

at 50 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.6b02673

upstream raw materials:

[tris(2-(diphenylphosphino)ethyl)amine]Co(COCH₃)

lithium triethylborohydride

sodium tetraphenyl borate

sodium tetrahydroborate

Downstream raw materials:

[(tris(2-(diphenylphosphino)ethyl)amine)Co(CO)]BPh₄

(tris[2-(diphenylphosphino)ethyl]amine)Co(η2-OCNPh)

Co(C₆H₁₂N(P(C₆H₅)2)3)(CS)⁽¹⁺⁾*B(C₆H₅)4^(1-)=Co(C₆H₁₂N(P(C₆H₅)2)3)CSB(C₆H₅)4

(tris[2-(diphenylphsophino)ethyl]amino)Co(η2-CS2)