methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate

Base Information

Chemical Name:methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate
CAS No.:252000-98-9
Molecular Formula:C₂₉H₄₂O₆Si₂
Molecular Weight:542.82
Hs Code.:

Synonyms:methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate

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Chemical Property of methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate

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Technology Process of methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate

There total 4 articles about methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 252000-94-5
methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-D-glucuronate)glycal

: 252000-98-9
methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate

Guidance literature:: With 3,3-dimethyldioxirane; In dichloromethane; acetone; at 20 ℃; for 2h;
DOI:10.1021/ja992608h

Reference yield:

: 57690-62-7
methyl 3,4-di-O-acetyl-1,2-dideoxy-D-arabino-hex-1-enopyranuronate

: 252000-98-9
methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate

Guidance literature:: Multi-step reaction with 4 steps

1: 86 percent / NaOMe / methanol / 1 h / 20 °C

2: imidazole / dimethylformamide / 2 h / 20 °C

3: imidazole / dimethylformamide / 4 h / 100 °C

4: 100 percent / dimethyldioxirane / acetone; CH₂Cl₂ / 2 h / 20 °C

With 1H-imidazole; sodium methylate; 3,3-dimethyldioxirane; In methanol; dichloromethane; N,N-dimethyl-formamide; acetone; 1: Deacetylation / 2: silylation / 3: silylation / 4: Epoxidation;
DOI:10.1021/ja992608h

Reference yield:

: 95530-80-6
methyl 1,2-dideoxy-D-arabino-hex-1-enopyranuronate

: 252000-98-9
methyl (3-O-tert-butyldimethylsilyl-4-O-tert-butyldiphenylsilyl-2,3-anhydro)-D-glucuronate

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 2 h / 20 °C

2: imidazole / dimethylformamide / 4 h / 100 °C

3: 100 percent / dimethyldioxirane / acetone; CH₂Cl₂ / 2 h / 20 °C

With 1H-imidazole; 3,3-dimethyldioxirane; In dichloromethane; N,N-dimethyl-formamide; acetone; 1: silylation / 2: silylation / 3: Epoxidation;
DOI:10.1021/ja992608h