Technology Process of 6,6,7,7-tetrachloro-1-octyl benzoate
There total 4 articles about 6,6,7,7-tetrachloro-1-octyl benzoate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sulfuryl dichloride;
In
dichloromethane; benzene;
for 96h;
Heating;
DOI:10.1021/ja00097a019
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 91 percent / triethylamine / CH2Cl2 / 1 h / 0 °C
2: 1.) LDA / 1.) THF, -78 deg C, 0.5 h, 2.) THF, overnight
3: 60 percent / sulfuryl chloride / benzene; CH2Cl2 / 96 h / Heating
With
sulfuryl dichloride; triethylamine; lithium diisopropyl amide;
In
dichloromethane; benzene;
DOI:10.1021/ja00097a019
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 83 percent / 1,2-diaminoethane, Li, potassium tert-butoxide / 3 h
2: 91 percent / triethylamine / CH2Cl2 / 1 h / 0 °C
3: 1.) LDA / 1.) THF, -78 deg C, 0.5 h, 2.) THF, overnight
4: 60 percent / sulfuryl chloride / benzene; CH2Cl2 / 96 h / Heating
With
sulfuryl dichloride; potassium tert-butylate; lithium; ethylenediamine; triethylamine; lithium diisopropyl amide;
In
dichloromethane; benzene;
DOI:10.1021/ja00097a019
