C₅₀H₅₂BrN₅O₁₃

Base Information

• Chemical Name: C₅₀H₅₂BrN₅O₁₃
• CAS No.: 94779-88-1
• Molecular Formula: C₅₀H₅₂BrN₅O₁₃
• Molecular Weight: 1010.89
• Mol file: 94779-88-1.mol

Synonyms:C₅₀H₅₂BrN₅O₁₃

Chemical Property of C₅₀H₅₂BrN₅O₁₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₀H₅₂BrN₅O₁₃

There total 15 articles about C₅₀H₅₂BrN₅O₁₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

C56H58BrN5O16 (94779-87-0,94904-20-8) → C50H52BrN5O13 (94779-88-1)

Guidance literature:

With potassium hydroxide; In methanol; for 2h; Ambient temperature;

DOI:10.1016/S0040-4039(01)81451-9

Reference yield:

6-bromoisatin (6326-79-0) → C50H52BrN5O13 (94779-88-1)

Guidance literature:

Multi-step reaction with 13 steps

1: 81 percent / AcOH, piperidine / benzene / 5 h / Heating

2: 92 percent / aq.Na₂S₂O₄ / ethanol / 10 h / Heating

3: 1.) hydrazine hydrate; 2.) HCl / 1.) THF-MeOH, -15 deg C, 30 min; 2.) from -15 deg C to 0 deg C for 2 h

4: NaHCO₃ / tetrahydrofuran; methanol / 2 h / Ambient temperature

5: pyridine / 2 h / 70 °C

6: 82 percent / NaBH₃CN, 2N HCl / ethyl acetate / 0.17 h / -10 °C

7: benzene / Ambient temperature

8: 85 percent / pyridine / 10 h / Ambient temperature

9: NaOAc / 1.5 h / 120 °C

10: 97 percent / m-CPBA / CH₂Cl₂

11: 61 percent / acetone / 2 h / Ambient temperature; 0.1M pH=10.2 NaHCO₃-Na₂CO₃ buffer

12: picrylchloride / pyridine / 1.5 h / Ambient temperature

13: 72 percent / 0.1 N KOH / methanol / 2 h / Ambient temperature

With piperidine; hydrogenchloride; potassium hydroxide; sodium dithionite; 2,4,6-trinitrochlorobenzene; sodium acetate; sodium cyanoborohydride; sodium hydrogencarbonate; hydrazine hydrate; acetic acid; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; pyridine; methanol; ethanol; dichloromethane; ethyl acetate; acetone; benzene;

DOI:10.1016/S0040-4039(01)81451-9

Reference yield:

(+/-)-1-O-benzoyl-2,3-cyclohexyledene-4,5-isopropylidene-3-methoxymethyl myo-inositol → C50H52BrN5O13 (94779-88-1)

Guidance literature:

Multi-step reaction with 3 steps

2: picrylchloride / pyridine / 1.5 h / Ambient temperature

3: 72 percent / 0.1 N KOH / methanol / 2 h / Ambient temperature

With potassium hydroxide; 2,4,6-trinitrochlorobenzene; In pyridine; methanol;

DOI:10.1016/S0040-4039(01)81451-9

upstream raw materials:

C₅₆H₅₈BrN₅O₁₆

6-bromoisatin

4-(ethylsulfonyl)-5-nitro-2,6-bis(phenylmethoxy)pyrimidine

2-[6-Bromo-2-oxo-1,2-dihydro-indol-(3E)-ylidene]-4-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-3-oxo-butyric acid 2-methylsulfanyl-ethyl ester

Downstream raw materials:

C₂₅H₂₄BrN₅O₁₂

(+/-)-surugatoxin

C₅₀H₅₂BrN₅O₁₃