bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan

Base Information

• Chemical Name: bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan
• CAS No.: 1034120-00-7
• Molecular Formula: C₂₂H₂₄F₆O₆S₃
• Molecular Weight: 594.617
• Mol file: 1034120-00-7.mol

Synonyms:bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan

Chemical Property of bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan

There total 1 articles about bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

trifluoromethylsulfonic anhydride (358-23-6) + 2,2'-thiobis<4-t-butylphenol> (3273-24-3) → bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan (1034120-00-7)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1246/cl.2008.418

Reference yield: 76.0%

bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan (1034120-00-7) + carbon monoxide (201230-82-2) → C24H30O4S

Guidance literature:

With 1,3-bis-(diphenylphosphino)propane; palladium diacetate; triethylamine; In methanol; dimethyl sulfoxide; at 70 ℃; for 18h; under 760.051 Torr;

DOI:10.1246/cl.2008.1228

Reference yield: 66.0%

bis[5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfan (1034120-00-7) + Diphenylphosphine oxide (4559-70-0) → bis[5-tert-butyl-2-(diphenylphosphinyl)phenyl]sulfan (1034120-02-9)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; 1,4-di(diphenylphosphino)-butane; palladium diacetate; In dimethyl sulfoxide; at 120 ℃; for 2.5h;

DOI:10.1246/cl.2008.418

upstream raw materials:

trifluoromethylsulfonic anhydride

2,2'-thiobis<4-t-butylphenol>

Downstream raw materials:

bis[5-tert-butyl-2-(diphenylphosphinyl)phenyl]sulfan

C₂₂H₂₆O₄S