Technology Process of 9-[2-(Diphenylphosphino)phenyl]-9H-carbazole, Min. 97% Ph PhenCar-Phos
There total 3 articles about 9-[2-(Diphenylphosphino)phenyl]-9H-carbazole, Min. 97% Ph PhenCar-Phos which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
9-(2-bromophenyl)-9H-carbazole;
With
n-butyllithium;
In
tetrahydrofuran;
at -78 ℃;
for 0.5h;
Inert atmosphere;
chloro-diphenylphosphine;
In
tetrahydrofuran;
at -78 - 20 ℃;
for 12h;
Inert atmosphere;
DOI:10.1021/acs.oprd.9b00246
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: copper(I) oxide; potassium phosphate; N,N-dimethylethylenediamine / toluene / 120 °C
2.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
With
copper(I) oxide; potassium phosphate; n-butyllithium; N,N-dimethylethylenediamine;
In
tetrahydrofuran; toluene;
DOI:10.1039/c1cc10708a
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: copper(I) oxide; potassium phosphate; N,N-dimethylethylenediamine / toluene / 120 °C
2.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
With
copper(I) oxide; potassium phosphate; n-butyllithium; N,N-dimethylethylenediamine;
In
tetrahydrofuran; toluene;
DOI:10.1039/c1cc10708a
