1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene

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Chemical Name:1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene
CAS No.:293313-30-1
Molecular Formula:C₄₉H₄₄F₆N₄O₄S₂
Molecular Weight:931.035
Hs Code.:

Synonyms:1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene

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Chemical Property of 1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene

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Technology Process of 1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene

There total 6 articles about 1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

: 14538-51-3,78375-92-5
2,3-bis(hydroxyamino)-2,3-dimethylbutane monosulfate

: 374625-47-5
1,2-Bis[6-(4-formylphenyl)-2-methyl-1-benzothiophen-3-yl]hexafluorocyclopentene

: 293313-30-1
1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene

Guidance literature:: 2,3-bis(hydroxyamino)-2,3-dimethylbutane monosulfate; 1,2-Bis[6-(4-formylphenyl)-2-methyl-1-benzothiophen-3-yl]hexafluorocyclopentene; With potassium carbonate; In methanol; Heating;

With sodium periodate; In dichloromethane; Further stages.;
DOI:10.1021/ja001767u

Reference yield:

: 87199-17-5
4-formylphenylboronic acid,

: 293313-30-1
1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 49 percent

2.1: K₂CO₃ / methanol / Heating

2.2: 13 percent / NaIO₄ / CH₂Cl₂

With potassium carbonate; In methanol; 1.1: Suzuki coupling / 2.1: Condensation / 2.2: Oxidation;
DOI:10.1021/ja001767u

Reference yield:

: 137814-07-4
1,2-bis(2-methyl-1-benzothiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopent-1-ene

: 293313-30-1
1,2-Bis{6-[4-(1-oxyl-3-oxide-4,4,5,5-tetramethylimidazolin-2-yl)phenyl]-2-methyl-1-benzothiophen-3-yl}hexafluorocyclopentene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 76 percent / I₂; H₅IO₆

2.1: 49 percent

3.1: K₂CO₃ / methanol / Heating

3.2: 13 percent / NaIO₄ / CH₂Cl₂

With iodine; potassium carbonate; periodic acid; In methanol; 1.1: Iodination / 2.1: Suzuki coupling / 3.1: Condensation / 3.2: Oxidation;
DOI:10.1021/ja001767u