(1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate

Base Information

Chemical Name:(1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate
CAS No.:1192356-88-9
Molecular Formula:C₂₃H₂₅NO₇S
Molecular Weight:459.52
Hs Code.:

Synonyms:(1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate

Chemical Property:

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Technology Process of (1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate

There total 3 articles about (1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1192356-86-7
(1S,2S,7R,8aS)-2-(benzoyloxy)-7-hydroxyoctahydro-1-indolizinyl benzoate

: 124-63-0
methanesulfonyl chloride

: 1192356-88-9
(1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/adsc.200800806

Reference yield:

: (4S,5S)-5-(benzoyloxy)-2-(2-hydroxyethyl)hexahydropyrrolo[1,2-b]isoxazol-4-yl benzoate

: 1192356-88-9
(1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane / 1 h / 0 °C / Inert atmosphere

2: palladium 10% on activated carbon; hydrogen / methanol / 760.05 Torr

3: triethylamine / dichloromethane / 2 h / 20 °C / Inert atmosphere

With palladium 10% on activated carbon; hydrogen; triethylamine; In methanol; dichloromethane;
DOI:10.1016/j.tet.2011.10.008

Reference yield:

: C₂₃H₂₅NO₈S

: 1192356-88-9
(1S,2S,7R,8aS)-1-(benzoyloxy)-7-[(methylsulfonyl)oxy]octahydro-2-indolizinyl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: palladium 10% on activated carbon; hydrogen / methanol / 760.05 Torr

2: triethylamine / dichloromethane / 2 h / 20 °C / Inert atmosphere

With palladium 10% on activated carbon; hydrogen; triethylamine; In methanol; dichloromethane;
DOI:10.1016/j.tet.2011.10.008