bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

Base Information

• Chemical Name: bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)
• CAS No.: 1160310-32-6
• Molecular Formula: C₄₇H₃₅N₅O₄Sn
• Molecular Weight: 852.536
• Mol file: 1160310-32-6.mol

Synonyms:bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

Chemical Property of bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

There total 2 articles about bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

5,15-bis(4-methyl)phenyl-10-(4-pyridyl)-20-(4-formatemethyl)phenyl porphyrin → bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) (1160310-32-6)

Guidance literature:

With pyridine; water; tin(ll) chloride; for 2h; Reflux;

DOI:10.1039/b902408p

Reference yield: 80.0%

tin(II) chloride dihdyrate (10025-69-1) + 5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrin → bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) (1160310-32-6)

Guidance literature:

In pyridine; mixt. of porphyrin and SnCl2*2H2O in pyridine refluxed for 2 h; CHCl3 and H2O added, org. phase sepd. and washed with H2O, dried over Na2SO4, filtrate evapd. to dryness, pptn. from CH2Cl2 with hexane;

DOI:10.1039/b902408p

Reference yield: 78.0%

bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) (1160310-32-6) + acetic acid (64-19-7,77671-22-8) → bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) (1160310-29-1)

Guidance literature:

With lithium hydroxide; In methanol; mixt. of Sn complex and 1 M aq. LiOH in MeOH stirred at 50°C overnight, soln. concd. under vac., aq. AcOH added; extraction with CHCl3, org. phase washed with H2O, dried over Na2SO4, filtrate evapd., residue recrystd. from CH2Cl2/hexane;

DOI:10.1039/b902408p

upstream raw materials:

tin(II) chloride dihdyrate

Downstream raw materials:

bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)