bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

Base Information

• Chemical Name: bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)
• CAS No.: 1160310-29-1
• Molecular Formula: C₅₀H₃₇N₅O₆Sn
• Molecular Weight: 922.584
• Mol file: 1160310-29-1.mol

Synonyms:bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

Chemical Property of bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

There total 1 articles about bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) (1160310-32-6) + acetic acid (64-19-7,77671-22-8) → bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) (1160310-29-1)

Guidance literature:

With lithium hydroxide; In methanol; mixt. of Sn complex and 1 M aq. LiOH in MeOH stirred at 50°C overnight, soln. concd. under vac., aq. AcOH added; extraction with CHCl3, org. phase washed with H2O, dried over Na2SO4, filtrate evapd., residue recrystd. from CH2Cl2/hexane;

DOI:10.1039/b902408p

Reference yield:

bisacetoxy(5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porphyrinato)tin(IV) (1160310-29-1) + 5,10,15-tris(4-tolyl)-20-(3-phenylfumaramide) zinc(II)-porphyrin → [5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porpyrinatotin(IV)*5,10,15-tris(4-tolyl)-20-(3-phenylfumaramide)zinc(II)-porphyrin]6 + [5,15-bis(4-tolyl)-10-(4-carboxyphenyl)-20-(4-pyridyl)porpyrinatotin(IV)*5,10,15-tris(4-tolyl)-20-(3-phenylfumaramide) zinc(II)-porphyrin]5

Guidance literature:

In chloroform-d1; detected by NMR spectroscopy;

DOI:10.1039/b902408p

upstream raw materials:

bishydroxy(5,15-bis(4-tolyl)-10-(4-methoxycarbonylphenyl)-20-(4-pyridyl)porphyrinato)tin(IV)

acetic acid