endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline

Base Information

Chemical Name:endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline
CAS No.:86557-81-5
Molecular Formula:C₂₀H₁₈N₂O₂
Molecular Weight:318.375
Hs Code.:

endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz<f>-isoindoline

Synonyms:endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline

Suppliers and Price of endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline

Chemical Property:

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Technology Process of endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline

There total 4 articles about endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 930-88-1
N-methylmaleimide

: 25473-60-3
2-benzyl-2H-isoindole

: 86557-81-5
endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline

Guidance literature:: In diethyl ether; for 2h; Ambient temperature;

Reference yield:

: 2142-01-0
N-benzylphthalimide

: 86557-81-5
endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline

Guidance literature:: Multi-step reaction with 2 steps

1: 61 percent / LiAlH₄; methanol / tetrahydrofuran / 0.5 h / -78 °C

2: 84 percent / CH₂Cl₂ / 2.5 h / 0 °C

With methanol; lithium aluminium tetrahydride; In tetrahydrofuran; dichloromethane; 2: Diels-Alder reaction;
DOI:10.1021/ja0658259

Reference yield:

: 100-46-9
benzylamine

: 86557-81-5
endo-4,9-benzylepimino-3a,9a-dihydro-2-methyl-1,3-dioxobenz-isoindoline

Guidance literature:: Multi-step reaction with 2 steps

1: acetonitrile; water / 1 h / 20 °C

2: dichloromethane / 0.08 h / 0 °C

In dichloromethane; water; acetonitrile; 2: |Diels-Alder Cycloaddition;