3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one

Base Information

Chemical Name:3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one
CAS No.:86863-45-8
Molecular Formula:C₃₃H₃₇IO₆
Molecular Weight:656.558
Hs Code.:

Synonyms:3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one

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Chemical Property of 3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one

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Technology Process of 3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one

There total 4 articles about 3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 86863-44-7
3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(chloroacetoxy)-19-nor-9β-podocarp-13-en-12-one

: 86863-45-8
3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one

Guidance literature:: With sodium iodide; In acetone; for 8h; Heating;
DOI:10.1021/jo00167a017

Reference yield:

: 86863-42-5
3β-(benzyloxy)-7α-hydroxy-8β-(hydroxymethyl)-19-nor-9β-podocarp-13-en-12-one

: 86863-45-8
3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / 4-(dimethylamino)pyridine / pyridine / 15 h / 25 °C

2: 84 percent / 4-(dimethylamino)pyridine / pyridine / 7 h / 0 °C

3: 92 percent / NaI / acetone / 8 h / Heating

With dmap; sodium iodide; In pyridine; acetone;
DOI:10.1021/jo00167a017

Reference yield:

: 3β-(benzyloxy)-8β-formyl-14α-methoxy-12-((trimethylsilyl)oxy)-19-nor-9β-podocarp-12-en-7-one

: 86863-45-8
3β-(benzyloxy)-8β-((benzoyloxy)methyl)-7α-(iodoacetoxy)-19-nor-9β-podocarp-13-en-12-one

Guidance literature:: Multi-step reaction with 4 steps

1: 85 mg / sodium bis(2-methoxyethoxy)aluminum hydride / toluene / 0.25 h / 0 °C

2: 98 percent / 4-(dimethylamino)pyridine / pyridine / 15 h / 25 °C

3: 84 percent / 4-(dimethylamino)pyridine / pyridine / 7 h / 0 °C

4: 92 percent / NaI / acetone / 8 h / Heating

With dmap; sodium bis(2-methoxyethoxy)aluminium dihydride; sodium iodide; In pyridine; acetone; toluene;
DOI:10.1021/jo00167a017