1-(4-methylphenylsulfonylmethyl)naphthalene

Base Information

• Chemical Name: 1-(4-methylphenylsulfonylmethyl)naphthalene
• CAS No.: 341020-84-6
• Molecular Formula: C₁₈H₁₆O₂S
• Molecular Weight: 296.39
• Mol file: 341020-84-6.mol

Synonyms:1-(4-methylphenylsulfonylmethyl)naphthalene

Chemical Property of 1-(4-methylphenylsulfonylmethyl)naphthalene

Chemical Property:

Purity/Quality:

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Technology Process of 1-(4-methylphenylsulfonylmethyl)naphthalene

There total 10 articles about 1-(4-methylphenylsulfonylmethyl)naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

sodium 4-methylbenzenesulfinate (824-79-3) + 1-Chloromethylnaphthalene (86-52-2) → 1-(4-methylphenylsulfonylmethyl)naphthalene (341020-84-6)

Guidance literature:

With tetrabutylammomium bromide; In water; acetone; benzene; at 85 ℃; for 3h;

DOI:10.1021/jacs.8b01660

Reference yield: 79.0%

N,N,N-trimethyl-1-(naphthalene-1-yl)methanaminium iodide (116265-10-2) + toluene-4-sulfonic acid hydrazide (1576-35-8) → 1-(4-methylphenylsulfonylmethyl)naphthalene (341020-84-6)

Guidance literature:

With caesium carbonate; In 1-methyl-pyrrolidin-2-one; at 120 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.tetlet.2020.151975

Reference yield: 63.0%

4-methyl-N'-(naphthalen-1-ylmethylene)benzenesulfonohydrazide (19350-73-3) → 1-(4-methylphenylsulfonylmethyl)naphthalene (341020-84-6)

Guidance literature:

With dipotassium hydrogenphosphate; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; In N,N-dimethyl-formamide; at 20 ℃; for 24h; Sealed tube; Inert atmosphere; Irradiation;

DOI:10.1021/acs.orglett.1c02369

upstream raw materials:

(naphthalene-1-yl)methyl p-tolyl sulfide

1-Chloromethylnaphthalene

p-toluenesulfonyl chloride

sodium 4-methylbenzenesulfinate