(6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene

Base Information

Chemical Name:(6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene
CAS No.:1380215-77-9
Molecular Formula:C₃₅H₆₃NO₃SSi₂
Molecular Weight:634.127
Hs Code.:

(6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene

Synonyms:(6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene

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Chemical Property of (6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene

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Technology Process of (6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene

There total 5 articles about (6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1380215-76-8
(6S,7E,9R,10S,11E)-9-isopropyl-7-[(R)-N-methyl-S-phenylsulfonimidoyl]-10-(triethylsilyloxy)trideca-1,7,11-trien-6-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1380215-77-9
(6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene

Guidance literature:: (6S,7E,9R,10S,11E)-9-isopropyl-7-[(R)-N-methyl-S-phenylsulfonimidoyl]-10-(triethylsilyloxy)trideca-1,7,11-trien-6-ol; With 1H-imidazole; In N,N-dimethyl-formamide; at 0 ℃; for 1h; Inert atmosphere;

tert-butyldimethylsilyl chloride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 20h; Inert atmosphere;
DOI:10.1002/chem.201103060

Reference yield:

: 918637-15-7
(1Z,3R,4S,5E)-3-isopropyl-1-[(S)-N-methyl-S-phenyl-sulfonimidoyl]-hepta-1,5-dien-4-ol

: 1380215-77-9
(6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene

Guidance literature:: Multi-step reaction with 4 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 0 °C / Inert atmosphere

1.2: 20 h / 0 - 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C / Inert atmosphere

2.2: 2 h / 0 °C / Inert atmosphere

3.1: tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

4.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 0 °C / Inert atmosphere

4.2: 20 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; n-butyllithium; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;
DOI:10.1002/chem.201103060

Reference yield:

: 918637-17-9
triethyl((1Z,3R,4S,5E)-3-isopropyl-1-[(S)-N-methyl-S-phenylsulfonimidoyl]hepta-1,5-dien-4-yloxy)silane

: 1380215-77-9
(6S,9R,10S)-11,11-diethyl-8-isopropyl-2,2,3,3-tetramethyl-5-(pent-4-enyl)-6-[(R)-N-methyl-S-phenylsulfonimidoyl]-9-((E)-prop-1-enyl)-4,10-dioxa-3,11-disilatridec-6-ene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C / Inert atmosphere

1.2: 2 h / 0 °C / Inert atmosphere

2.1: tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

3.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 0 °C / Inert atmosphere

3.2: 20 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; n-butyllithium; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;
DOI:10.1002/chem.201103060