C₆₁H₅₈N₆O₉

Base Information

• Chemical Name: C₆₁H₅₈N₆O₉
• CAS No.: 1471985-06-4
• Molecular Formula: C₆₁H₅₈N₆O₉
• Molecular Weight: 1019.17
• Mol file: 1471985-06-4.mol

Synonyms:C₆₁H₅₈N₆O₉

Chemical Property of C₆₁H₅₈N₆O₉

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₁H₅₈N₆O₉

There total 5 articles about C₆₁H₅₈N₆O₉ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

C46H49N5O11 (1471984-89-0) + 4-(diphenylamino)benzaldehyde (4181-05-9) → C61H58N6O9 (1471985-06-4)

Guidance literature:

C₄₆H₄₉N₅O₁₁; With bis-triphenylphosphine-palladium(II) chloride; 4-nitro-phenol; tri-n-butyl-tin hydride; In dichloromethane; at 20 ℃; for 0.166667h; Inert atmosphere;

4-(diphenylamino)benzaldehyde; With acetic acid; In dichloromethane; at 20 ℃; for 0.166667h; Inert atmosphere;

DOI:10.1021/ja405776a

Reference yield:

L-leucine (61-90-5,21675-61-6,25248-98-0,70-45-1) → C61H58N6O9 (1471985-06-4)

Guidance literature:

Multi-step reaction with 4 steps

1.1: 1H-imidazole / 1 h / 100 °C / Inert atmosphere

2.1: triethylamine; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate / N,N-dimethyl-formamide / 0.17 h / 20 °C / Inert atmosphere

3.1: triethylamine; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate / N,N-dimethyl-formamide / 0.5 h / 20 °C / Inert atmosphere

4.1: 4-nitro-phenol; tri-n-butyl-tin hydride; bis-triphenylphosphine-palladium(II) chloride / dichloromethane / 0.17 h / 20 °C / Inert atmosphere

4.2: 0.17 h / 20 °C / Inert atmosphere

With 1H-imidazole; bis-triphenylphosphine-palladium(II) chloride; 4-nitro-phenol; tri-n-butyl-tin hydride; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; triethylamine; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/ja405776a

Reference yield:

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → C61H58N6O9 (1471985-06-4)

Guidance literature:

Multi-step reaction with 4 steps

1.1: 1H-imidazole / 1 h / 100 °C / Inert atmosphere

2.1: triethylamine; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate / N,N-dimethyl-formamide / 0.17 h / 20 °C / Inert atmosphere

3.1: triethylamine; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate / N,N-dimethyl-formamide / 0.5 h / 20 °C / Inert atmosphere

4.1: 4-nitro-phenol; tri-n-butyl-tin hydride; bis-triphenylphosphine-palladium(II) chloride / dichloromethane / 0.17 h / 20 °C / Inert atmosphere

4.2: 0.17 h / 20 °C / Inert atmosphere

With 1H-imidazole; bis-triphenylphosphine-palladium(II) chloride; 4-nitro-phenol; tri-n-butyl-tin hydride; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; triethylamine; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/ja405776a

upstream raw materials:

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

C₄₀H₃₉N₃O₉

C₄₆H₄₉N₅O₁₁

4-(diphenylamino)benzaldehyde

Downstream raw materials:

C₅₉H₅₂N₆O₈