6-phenyl-3,9-di(9,9-dimethylfluorene-2-yl)-5H-dibenzo[d,f][1,3]diazepine

Base Information

Chemical Name:6-phenyl-3,9-di(9,9-dimethylfluorene-2-yl)-5H-dibenzo[d,f][1,3]diazepine
CAS No.:1462367-14-1
Molecular Formula:C₄₉H₃₈N₂
Molecular Weight:654.854
Hs Code.:

Synonyms:6-phenyl-3,9-di(9,9-dimethylfluorene-2-yl)-5H-dibenzo[d,f][1,3]diazepine

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Chemical Property of 6-phenyl-3,9-di(9,9-dimethylfluorene-2-yl)-5H-dibenzo[d,f][1,3]diazepine

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Technology Process of 6-phenyl-3,9-di(9,9-dimethylfluorene-2-yl)-5H-dibenzo[d,f][1,3]diazepine

There total 2 articles about 6-phenyl-3,9-di(9,9-dimethylfluorene-2-yl)-5H-dibenzo[d,f][1,3]diazepine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 1462367-16-3
3,9-dibromo-6-phenyl-5H-dibenzo[d,f][1,3]diazepine

: 569343-09-5
2-(9,9-dimethyl-9H-fluoren-2-yl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

: 1462367-14-1
6-phenyl-3,9-di(9,9-dimethylfluorene-2-yl)-5H-dibenzo[d,f][1,3]diazepine

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutylammomium bromide; potassium carbonate; In tetrahydrofuran; toluene; at 110 ℃; for 24h; Schlenk technique; Inert atmosphere;
DOI:10.1016/j.tetlet.2013.08.107

Reference yield:

: 136630-36-9
4,4′-dibromo-[1,1′-biphenyl]-2,2′-diamine

: 1462367-14-1
6-phenyl-3,9-di(9,9-dimethylfluorene-2-yl)-5H-dibenzo[d,f][1,3]diazepine

Guidance literature:: Multi-step reaction with 2 steps

1: iodine; potassium carbonate / tert-butyl alcohol / 2 h / 70 °C

2: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutylammomium bromide / tetrahydrofuran; toluene / 24 h / 110 °C / Schlenk technique; Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutylammomium bromide; iodine; potassium carbonate; In tetrahydrofuran; toluene; tert-butyl alcohol; 2: |Suzuki Coupling;
DOI:10.1016/j.tetlet.2013.08.107