(E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde

Base Information

Chemical Name:(E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde
CAS No.:1164114-94-6
Molecular Formula:C₄₂H₆₈O₉Si₂
Molecular Weight:773.168
Hs Code.:

(E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde

Synonyms:(E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde

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Chemical Property of (E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde

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Technology Process of (E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde

There total 1 articles about (E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1164115-13-2
C₄₂H₇₀O₉Si₂

: 1164114-94-6
(E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde

Guidance literature:: With manganese(IV) oxide; In dichloromethane; for 12h; Inert atmosphere; Reflux;
DOI:10.1021/ol900757k

Reference yield: 98.0%

: 1055224-29-7
(R)-3-butyryl-4-isopropyloxazolidin-2-one

: 1164114-94-6
(E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde

: 1164114-95-7
(4R)-3-((2R,3S,E)-5-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)-2-ethyl-3-hydroxypent-4-enoyl)-4-isopropyloxazolidin-2-one

Guidance literature:: (R)-3-butyryl-4-isopropyloxazolidin-2-one; With di-n-butylboryl trifluoromethanesulfonate; triethylamine; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

(E)-3-((4R,5R)-4-(2-(tert-butyldimethylsilyloxy)ethyl)-2-(2,4-dimethoxyphenyl)-5-((R)-3-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)propyl)-1,3-dioxolan-4-yl)acrylaldehyde; In dichloromethane; at -78 - -20 ℃; Inert atmosphere;

With water; sodium hydrogencarbonate; In dichloromethane; at -20 ℃; optical yield given as %de;
DOI:10.1021/ol900757k