fac-[Mn(CO)3(3⁽⁵⁾-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4]

Base Information

Chemical Name:fac-[Mn(CO)3(3⁽⁵⁾-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4]
CAS No.:936086-22-5
Molecular Formula:C₂₄H₃₆MnN₆O₃*C₃₂H₁₂BF₂₄
Molecular Weight:1374.75
Hs Code.:

fac-[Mn(CO)3(3<sup>(5)</sup>-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4]

Synonyms:fac-[Mn(CO)3(3⁽⁵⁾-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4]

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Chemical Property of fac-[Mn(CO)3(3⁽⁵⁾-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4]

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Technology Process of fac-[Mn(CO)3(3⁽⁵⁾-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4]

There total 1 articles about fac-[Mn(CO)3(3⁽⁵⁾-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 14516-54-2
bromopentacarbonylmanganese(I)

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 15802-80-9
5-tert-butyl-1H-pyrazole

: 936086-22-5
fac-[Mn(CO)3(3⁽⁵⁾-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4]

Guidance literature:: With AgOSO₂CF₃; In dichloromethane; byproducts: AgBr; (N2, Schlenk) Ag-salt was added to a soln. of MnBr(CO)5 in CH2Cl2, stirred in the dark for 15 min, AgBr was filtered, evapd., dissolved in toluene, pyrazole was added, refluxed for 20 min, evapd., Na-salt was added to CH2Cl2-soln., stirred for 15 min; filtered, reduced in vol., hexane was added, the solid was washed with hexane, slow diffusion of hexane into a CH2Cl2-soln. of complex; elem. anal.;
DOI:10.1021/ic0700046

Reference yield:

: 936086-22-5
fac-[Mn(CO)3(3⁽⁵⁾-tert-butylpyrazole)3][B(3,5-bis(trifluoromethyl)phenyl)4]

: tetrabutylammonium perrhenate

: fac-[Mn(CO)3(3-tert-butylpyrazole)3][NBu₄][ReO₄][B(3,5-bis(trifluoromethyl)phenyl)4]

Guidance literature:: In hexane; dichloromethane; slow diffusion of hexane into a CH2Cl2-soln. of equimolar mixt. of Mn- and Re-compounds;
DOI:10.1021/ic0700046