Aspergiterpenoid E

Base Information

Chemical Name:Aspergiterpenoid E
CAS No.:288299-08-1
Molecular Formula:C₁₅H₂₂O₃
Molecular Weight:250.338
Hs Code.:

Synonyms:Aspergiterpenoid E

Suppliers and Price of Aspergiterpenoid E

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Aspergiterpenoid E

Chemical Property:

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Technology Process of Aspergiterpenoid E

There total 9 articles about Aspergiterpenoid E which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 288299-07-0
3-Hydroxy-4-((R)-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-benzoic acid ethyl ester

: 288299-08-1
Aspergiterpenoid E

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 1h;

Reference yield:

: 13837-60-0
2-ethynyl-2,6,6-trimethyl-3,4,5,6-tetrahydro-(2H)-pyran

: 288299-08-1
Aspergiterpenoid E

Guidance literature:: Multi-step reaction with 10 steps

1.1: KMnO₄; H₂O / acetone / 4 h / 0 - 20 °C

1.2: (R)-(+)-1-phenylethylamine

2.1: diethyl ether

3.1: LiAlH₄ / diethyl ether

4.1: (COCl)2; DMSO; Et₃N / 2 h / -78 - 20 °C

5.1: CHCl₃ / 8 h / Heating

6.1: DIBALH / 1 h / 0 °C

7.1: MnO₂ / CHCl₃ / 10 h / Heating

8.1: 86 percent / CHCl₃ / 10 h / Heating

9.1: (CF₃CO)2O; Et₃N / tetrahydrofuran / 2 h / 20 °C

9.2: 73 percent / NaBH₄ / ethanol / 0.5 h

10.1: 94 percent / LiAlH₄ / diethyl ether / 1 h / 0 °C

With manganese(IV) oxide; potassium permanganate; lithium aluminium tetrahydride; oxalyl dichloride; water; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride; In tetrahydrofuran; diethyl ether; chloroform; acetone; 1.1: Oxidation / 1.2: resolution of racemate / 2.1: Esterification / 3.1: Reduction / 4.1: Swern oxidation / 5.1: Wittig olefination / 6.1: Reduction / 7.1: Oxidation / 8.1: Wittig olefination / 9.1: Aromatisation / 9.2: Reduction / 10.1: Reduction;

Reference yield:

: 13226-32-9
(R)-(-)-Cinenic acid methyl ester

: 288299-08-1
Aspergiterpenoid E

Guidance literature:: Multi-step reaction with 8 steps

1.1: LiAlH₄ / diethyl ether

2.1: (COCl)2; DMSO; Et₃N / 2 h / -78 - 20 °C

3.1: CHCl₃ / 8 h / Heating

4.1: DIBALH / 1 h / 0 °C

5.1: MnO₂ / CHCl₃ / 10 h / Heating

6.1: 86 percent / CHCl₃ / 10 h / Heating

7.1: (CF₃CO)2O; Et₃N / tetrahydrofuran / 2 h / 20 °C

7.2: 73 percent / NaBH₄ / ethanol / 0.5 h

8.1: 94 percent / LiAlH₄ / diethyl ether / 1 h / 0 °C

With manganese(IV) oxide; lithium aluminium tetrahydride; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride; In tetrahydrofuran; diethyl ether; chloroform; 1.1: Reduction / 2.1: Swern oxidation / 3.1: Wittig olefination / 4.1: Reduction / 5.1: Oxidation / 6.1: Wittig olefination / 7.1: Aromatisation / 7.2: Reduction / 8.1: Reduction;