5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-pyridine

Base Information

• Chemical Name: 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-pyridine
• CAS No.: 1189524-15-9
• Molecular Formula: C₄₇H₁₈F₁₅IrN₆
• Molecular Weight: 1143.9
• Mol file: 1189524-15-9.mol

Synonyms:5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-pyridine

Chemical Property of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-pyridine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-pyridine

There total 3 articles about 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

pyridine (110-86-1) + bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + 5,10,15-tris(pentafluorophenyl)corrole → 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-pyridine (1189524-15-9)

Guidance literature:

bis(1,5-cyclooctadiene)diiridium(I) dichloride; 5,10,15-tris(pentafluorophenyl)corrole; With potassium carbonate; In tetrahydrofuran; for 1.5h; Inert atmosphere; Reflux;

pyridine; In tetrahydrofuran;

Reference yield: 50.0%

pyridine (110-86-1) + 5,10,15-tris(pentafluorophenyl)corrole → 5,10,15-tris(pentafluorophenylcorrolato)iridium(III) bis(pyridine) (1189524-15-9)

Guidance literature:

5,10,15-tris(pentafluorophenyl)corrole; With bis(1,5-cyclooctadiene)diiridium(I) dichloride; potassium carbonate; In tetrahydrofuran; for 1.5h; Reflux; Inert atmosphere;

pyridine; In tetrahydrofuran; at 20 ℃;

DOI:10.1021/ja101647t

Reference yield: 50.0%

pyridine (110-86-1) + bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + 5,10,15-tris(pentafluorophenyl)corrole → 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-pyridine (1189524-15-9)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; (Ar) suspn. Ir complex, ligand and K2CO3 in THF was refluxed for 90 min,pyridine was added, allowed to cool to room temp. on air; column chromy. on silica;

DOI:10.1021/ic901164r

upstream raw materials:

pyridine

bis(1,5-cyclooctadiene)diiridium(I) dichloride