Technology Process of C58H85NO14Si
There total 13 articles about C58H85NO14Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
pyridinium p-toluenesulfonate;
In
methanol;
at 20 ℃;
DOI:10.1021/jo9609337
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 84 percent / DIBAL / CH2Cl2
2.1: 53 percent / PCC / CH2Cl2
3.1: CH2Cl2
4.1: (nBu3Sn)2O / CH2Cl2 / 20 °C
4.2: 88 percent / t-BuOCl / CH2Cl2 / 8 h / -46 - 20 °C
5.1: 81 percent / Mo(CO)6 / acetonitrile; H2O / 70 °C
6.1: 90 percent / PPTs / methanol / 20 °C
With
hexacarbonyl molybdenum; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; pyridinium chlorochromate; bis(tri-n-butyltin)oxide;
In
methanol; dichloromethane; water; acetonitrile;
1.1: Reduction / 2.1: Oxidation / 3.1: Evans asymmetric aldol condensation / 4.1: stannylation / 4.2: Cycloaddition / 5.1: Ring cleavage / 6.1: Methylation;
DOI:10.1021/jo9609337
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: NEt3 / CH2Cl2
2.1: CH2Cl2
3.1: (nBu3Sn)2O / CH2Cl2 / 20 °C
3.2: 88 percent / t-BuOCl / CH2Cl2 / 8 h / -46 - 20 °C
4.1: 81 percent / Mo(CO)6 / acetonitrile; H2O / 70 °C
5.1: 90 percent / PPTs / methanol / 20 °C
With
hexacarbonyl molybdenum; pyridinium p-toluenesulfonate; triethylamine; bis(tri-n-butyltin)oxide;
In
methanol; dichloromethane; water; acetonitrile;
1.1: enolization / 2.1: Evans asymmetric aldol condensation / 3.1: stannylation / 3.2: Cycloaddition / 4.1: Ring cleavage / 5.1: Methylation;
DOI:10.1021/jo9609337
