Re(C₅NH₄C₅NH₄)(CO)3(C₅NH₄CH₂NHCH₂C₆H₅)⁽¹⁺⁾*PF₆^(1-)=(Re(C₁₀N₂H₈)(CO)3(C₁₃N₂H₁₄))PF₆

Base Information

• Chemical Name: Re(C₅NH₄C₅NH₄)(CO)3(C₅NH₄CH₂NHCH₂C₆H₅)⁽¹⁺⁾*PF₆^(1-)=(Re(C₁₀N₂H₈)(CO)3(C₁₃N₂H₁₄))PF₆
• CAS No.: 148861-25-0
• Molecular Formula: C₂₆H₂₂N₄O₃Re*F₆P
• Molecular Weight: 769.657
• Mol file: 148861-25-0.mol

Synonyms:Re(C₅NH₄C₅NH₄)(CO)3(C₅NH₄CH₂NHCH₂C₆H₅)⁽¹⁺⁾*PF₆^(1-)=(Re(C₁₀N₂H₈)(CO)3(C₁₃N₂H₁₄))PF₆

Chemical Property of Re(C₅NH₄C₅NH₄)(CO)3(C₅NH₄CH₂NHCH₂C₆H₅)⁽¹⁺⁾*PF₆^(1-)=(Re(C₁₀N₂H₈)(CO)3(C₁₃N₂H₁₄))PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Re(C₅NH₄C₅NH₄)(CO)3(C₅NH₄CH₂NHCH₂C₆H₅)⁽¹⁺⁾*PF₆^(1-)=(Re(C₁₀N₂H₈)(CO)3(C₁₃N₂H₁₄))PF₆

There total 2 articles about Re(C₅NH₄C₅NH₄)(CO)3(C₅NH₄CH₂NHCH₂C₆H₅)⁽¹⁺⁾*PF₆^(1-)=(Re(C₁₀N₂H₈)(CO)3(C₁₃N₂H₁₄))PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Re(C5NH4C5NH4)(CO)3(C5NH4CH2NHCH(C6H5)CH(C6H5)OH)(1+)*PF6(1-)=(Re(C10N2H8)(CO)3(C20N2H20O))PF6 → Re(C5NH4C5NH4)(CO)3(C5NH4CH2NHCH2C6H5)(1+)*PF6(1-)=(Re(C10N2H8)(CO)3(C13N2H14))PF6 (148861-25-0)

Guidance literature:

With sodium cyanoborohydride; In acetonitrile; byproducts: benzaldehyde, H2; Irradiation (UV/VIS); a soln. of the Re-complex in Ar-degassed CH3CN is irradiated (366 nm, medium- or high-pressure Hg lamp), overnight incubation with with a 5-fold excess of NaBH3(CN); Kinetics;

DOI:10.1021/ja00066a037

Reference yield:

silver(I) hexafluorophosphate (26042-63-7) + tricarbonyl(2,2'-bipyridine)chlororhenium(I) (55658-96-3) + 4-<(N-benzylamino)methyl>pyridine (73325-67-4) → Re(C5NH4C5NH4)(CO)3(C5NH4CH2NHCH2C6H5)(1+)*PF6(1-)=(Re(C10N2H8)(CO)3(C13N2H14))PF6 (148861-25-0)

Guidance literature:

In N,N-dimethyl-formamide; the Re-complex, AgPF6 and the ligand were dissolved in DMF under Ar, heated to 75°C for 2-3 h; filtered, evapd. under reduced pressure, chromy. on alumina;

DOI:10.1021/ja00066a037

upstream raw materials:

silver(I) hexafluorophosphate

tricarbonyl(2,2'-bipyridine)chlororhenium(I)

4-<(N-benzylamino)methyl>pyridine

Refernces