tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate}

Base Information

• Chemical Name: tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate}
• CAS No.: 141293-59-6
• Molecular Formula: C₁₂H₁₀BFeO₂*C₁₆H₃₆N
• Molecular Weight: 495.337
• Mol file: 141293-59-6.mol

Synonyms:tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate}

Chemical Property of tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate}

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate}

There total 1 articles about tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tricarbonyl(η5-1-phenylborole)iron (103652-93-3) + tetra(n-butyl)ammonium hydrogensulfate (32503-27-8) → tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate} (141293-59-6)

Guidance literature:

In sodium hydroxide; benzene; N2 atmosphere; layering of soln. of NBu4HSO4 in aq. NaOH with soln. of Fe-compd. in benzene, stirring (15 h, room temp.); evapn. to dryness of org. layer, washing of residue (pentane), drying (vac.); elem. anal.;

Reference yield: 64.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate} (141293-59-6) → [η(5)-(1-phenylborole)]Fe(CO)2(AuPPh3)2

Guidance literature:

With Et₃N; In acetone; N2-atmosphere; fitering, drying, CH2Cl2 addn., chromy. (SiO2), evapn. (vac.), crystn. (Me2CO); elem. anal.;

DOI:10.1021/om9703189

Reference yield: 27.0%

tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate} (141293-59-6) + trans-Pt(γ-picoline)2Br2 (52614-04-7,77287-08-2) → Pt(NC5H4CH3)2(FeH(CO)2(C4H4BC6H5))2

Guidance literature:

In dichloromethane; (N2); stirring (-78°C to room temp.); filtration (silica gel), crystn. (CH2Cl2/toluene, -25°C); elem. anal.;

DOI:10.1039/a903846i

upstream raw materials:

tricarbonyl(η5-1-phenylborole)iron

tetra(n-butyl)ammonium hydrogensulfate

Downstream raw materials:

trans-chlorohydridobis(triphenylphosphine)platinum(II)