tricarbonyl(η5-1-phenylborole)iron

Base Information

Chemical Name:tricarbonyl(η5-1-phenylborole)iron
CAS No.:103652-93-3
Molecular Formula:C₁₃H₉BFeO₃
Molecular Weight:279.871
Hs Code.:

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Chemical Property of tricarbonyl(η5-1-phenylborole)iron

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Technology Process of tricarbonyl(η5-1-phenylborole)iron

There total 1 articles about tricarbonyl(η5-1-phenylborole)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 84017-49-2
1-phenyl-2,5-dihydro-1H-borole

: 103652-93-3
tricarbonyl(η5-1-phenylborole)iron

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); (N2); irradiated (26 h, 10-15°C); refluxed (5-6 h); volatiles removed (vac.); chromd. (Al2O3, pentane); evapd.; cooled stepwise to -80°C; elem. anal.;
DOI:10.1016/S0022-328X(00)99531-7

Reference yield: 99.0%

: 103652-93-3
tricarbonyl(η5-1-phenylborole)iron

: 32503-27-8
tetra(n-butyl)ammonium hydrogensulfate

: 141293-59-6
tetra-n-butylammonium {dicarbonylhydrido(η5-(1-phenylborole))ferrate}

Guidance literature:: In sodium hydroxide; benzene; N2 atmosphere; layering of soln. of NBu4HSO4 in aq. NaOH with soln. of Fe-compd. in benzene, stirring (15 h, room temp.); evapn. to dryness of org. layer, washing of residue (pentane), drying (vac.); elem. anal.;

Reference yield: 97.0%

: 103652-93-3
tricarbonyl(η5-1-phenylborole)iron

: 5259-72-3,10060-40-9,111-78-4
cyclo-octa-1,5-diene

: 123038-07-3
(η4-1,5-cyclooctadiene)carbonyl{η5-(1-phenylborole)}iron

Guidance literature:: In hexane; byproducts: CO; Irradiation (UV/VIS); irradn. of soln. of the (η5-borole)tricarbonyl-iron complex and cyclooctadiene under N2 (10-15°C, mercury vapor lamp, 70 min; excess diene); filtration, washing with a small amount of pentane; elem. anal.;
DOI:10.1016/0022-328X(89)87245-6