Chloro-acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-chloro-tetrahydro-pyran-2-ylmethyl ester

Base Information

Chemical Name:Chloro-acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-chloro-tetrahydro-pyran-2-ylmethyl ester
CAS No.:88988-64-1
Molecular Formula:C₂₉H₃₀Cl₂O₆
Molecular Weight:545.46
Hs Code.:

Synonyms:Chloro-acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-chloro-tetrahydro-pyran-2-ylmethyl ester

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Chemical Property of Chloro-acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-chloro-tetrahydro-pyran-2-ylmethyl ester

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Technology Process of Chloro-acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-chloro-tetrahydro-pyran-2-ylmethyl ester

There total 6 articles about Chloro-acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-chloro-tetrahydro-pyran-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 109914-65-0,109914-88-7
2,3,4-tri-O-benzyl-1,6-di-O-chloroacetyl-L-idopyranose

: 88988-64-1,109914-66-1
2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-L-idopyranosyl chloride

Guidance literature:: With hydrogenchloride; In dichloromethane; at 0 ℃; for 3h;
DOI:10.1016/S0008-6215(00)90218-0

Reference yield:

: 88988-63-0
Chloro-acetic acid (2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-hydroxy-tetrahydro-pyran-2-ylmethyl ester

: 88988-64-1
Chloro-acetic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-chloro-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: With <(chlorosulfinyloxy)methylene>dimethylammonium chloride; In 1,2-dichloro-ethane; Yield given;
DOI:10.1016/0008-6215(83)88396-7

Reference yield:

: 2771-55-3,47727-91-3,47727-92-4,47727-93-5,48229-09-0,48229-10-3,71117-16-3,90638-67-8,107797-96-6,109958-32-9,109958-34-1,142392-93-6,142392-94-7,142392-95-8
2,3,4-tri-O-benzyl-L-idopyranose

: 88988-64-1,109914-66-1
2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-L-idopyranosyl chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / pyridine / CH₂Cl₂ / 1 h / 0 °C

2: 90 percent / hydrogen chloride / CH₂Cl₂ / 3 h / 0 °C

With pyridine; hydrogenchloride; In dichloromethane;
DOI:10.1016/S0008-6215(00)90218-0