(1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

Base Information

Chemical Name:(1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate
CAS No.:172472-91-2
Molecular Formula:C₂₁H₃₁NO₅
Molecular Weight:377.481
Hs Code.:

Synonyms:(1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

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Chemical Property of (1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

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Technology Process of (1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

There total 3 articles about (1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 172472-88-7
(1S,2R)-(E)-bis(1,1-dimethylethyl) N-(hydroperoxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

: 172472-91-2
(1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

Guidance literature:: With triphenylphosphine; In tetrachloromethane; at -25 ℃; for 0.0833333h;
DOI:10.1111/j.1751-1097.1999.tb08241.x

Reference yield:

: 172472-87-6
(S,Z)-bis(1,1-dimethylethyl) N-(1-methyl-4-phenylbut-2-enyl)-imidodicarbonate

: 172472-91-2
(1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

Guidance literature:: Multi-step reaction with 2 steps

1: O₂ / CCl₄ / 5 h / -25 °C / Irradiation

2: 62 percent / PPh₃ / CCl₄ / 0.08 h / -25 °C

With oxygen; triphenylphosphine; In tetrachloromethane; 1: Oxidation / 2: Reduction;
DOI:10.1111/j.1751-1097.1999.tb08241.x

Reference yield:

: (RS,Z)-bis(1,1-dimethylethyl) N-(1-methyl-4-phenylbut-2-enyl)-imidodicarbonate

: (1R,2S,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

: 172472-91-2
(1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate

Guidance literature:: With oxygen; 5,15,10,20-tetraphenylporphyrin; triphenylphosphine; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) CCl₄, irradiation, -25 deg C, 5 h; 2.) CCl₄, -25 deg C, 5 min;
DOI:10.1055/s-1995-4071