172472-88-7

Upstream product

• 172472-87-6 (S,Z)-bis(1,1-dimethylethyl) N-(1-methyl-4-phenylbut-2-enyl)-imidodicarbonate 

Downstream Products

• 172472-91-2 (1S,2R,E)-bis(1,1-dimethylethyl) N-(2-hydroxy-1-methyl-4-phenylbut-3-enyl)imidodicarbonate 
• 107673-74-5 (3R,4S)-4-Amino-1-phenyl-1-penten-3-ol 

Relevant academic research and scientific papers

Stereocontrolled photooxygenations - A valuable synthetic tool

The stereochemical course of the singlet-oxygen ene reaction with acyclic olefins may be controlled if in the substrate conformational fixation (1,3-allylic strain) an allylic substituent for interaction with the attacking oxygen enophile aligns. Various

Diastereoselective synthesis of merucathin: The singlet oxygen ene reaction (Schenck reaction) as a key step towards an E-configured β-amino allylic alcohol

An enantio- and diastereoselective synthesis of the naturally occurring merucathin is reported. The singlet oxygen ene reaction of the bis-Boc-protected allylic amine 3, which was prepared from L-alanine, was employed as key step for this regio- and diast