10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole

Base Information

Chemical Name:10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole
CAS No.:1260854-67-8
Molecular Formula:C₆₃H₆₃CoN₄O₃
Molecular Weight:983.211
Hs Code.:

Synonyms:10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole

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Chemical Property of 10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole

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Technology Process of 10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole

There total 8 articles about 10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(4-tert-butylphenyl)corrole

: 1260854-67-8
10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole

Guidance literature:: With cobalt(II) acetate; In acetonitrile; at 85 - 95 ℃; for 0.333333h; Microwave irradiation;
DOI:10.1021/ja108904s

Reference yield: 89.0%

: 10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)corrole

: 7732-18-5
water

: 71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7
cobalt(II) acetate

: 1260854-67-8
10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole

Guidance literature:: In acetonitrile; other Radiation; a microwave glass tube was charged with CH3CN and corrole, the soln. was stirred at room temp. for 10 min, Co-salt was added, stirred for 10 min, sealed, subjected to microwave irradiation at 85°C for 20 min,cooled to room temp.; column chromy. on silica gel (CHCl3 -> CHCl3:CH3OH (100:1) -> CHCl3:CH3OH (10:1)); elem. anal.;
DOI:10.1021/ja108904s

Reference yield:

: 405175-86-2
5-bromo-2,7-di-tert-butyl-9,9-dimethylxanthene-4-carbaldehyde

: 1260854-67-8
10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene))-5,15-bis(4-tert-butylphenyl)cobaltcorrole

Guidance literature:: Multi-step reaction with 6 steps

1.1: toluene-4-sulfonic acid / toluene / Inert atmosphere; Reflux

2.1: phenyllithium / tetrahydrofuran; hexane

3.1: sulfuric acid / Reflux

4.1: trifluoroacetic acid / dichloromethane / 7 h / 20 °C

4.2: 0.25 h / 20 °C

5.1: sodium hydroxide / tetrahydrofuran; water / 8 h / 75 - 85 °C / Microwave irradiation

5.2: 20 °C

6.1: cobalt(II) acetate / acetonitrile / 0.33 h / 85 - 95 °C / Microwave irradiation

With sulfuric acid; cobalt(II) acetate; toluene-4-sulfonic acid; phenyllithium; trifluoroacetic acid; sodium hydroxide; In tetrahydrofuran; hexane; dichloromethane; water; toluene; acetonitrile;
DOI:10.1021/ja108904s