6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde

Base Information

Chemical Name:6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde
CAS No.:1572185-77-3
Molecular Formula:C₃₉H₃₄N₂O₂S₂
Molecular Weight:626.843
Hs Code.:

Synonyms:6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde

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Chemical Property of 6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde

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Technology Process of 6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde

There total 5 articles about 6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 1572185-76-2
4-(4-(hexyloxy)phenyl)-6-iodo-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde

: 201802-67-7
4-(diphenylamino)phenyl boronic acid

: 1572185-77-3
6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; 1,2-dimethoxyethane; Reflux;
DOI:10.1016/j.tet.2014.02.002

Reference yield:

: 51751-44-1
3,3'dibromo-2,2'-bithiophene

: 1572185-77-3
6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium tert-butylate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; 1,1'-bis-(diphenylphosphino)ferrocene / toluene / 0.25 h / 20 °C

1.2: Reflux

2.1: trichlorophosphate / 1,2-dichloro-ethane / 0 - 20 °C / Reflux

3.1: N-iodo-succinimide; acetic acid / chloroform / 20 °C / Darkness

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran; 1,2-dimethoxyethane / Reflux

With 1,1'-bis-(diphenylphosphino)ferrocene; N-iodo-succinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium tert-butylate; potassium carbonate; acetic acid; trichlorophosphate; In tetrahydrofuran; 1,2-dimethoxyethane; chloroform; 1,2-dichloro-ethane; toluene;
DOI:10.1016/j.tet.2014.02.002

Reference yield:

: 39905-57-2
4-(n-hexyloxy)aniline

: 1572185-77-3
6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno[3,2-b:2',3'-d]pyrrole-2-carbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium tert-butylate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; 1,1'-bis-(diphenylphosphino)ferrocene / toluene / 0.25 h / 20 °C

1.2: Reflux

2.1: trichlorophosphate / 1,2-dichloro-ethane / 0 - 20 °C / Reflux

3.1: N-iodo-succinimide; acetic acid / chloroform / 20 °C / Darkness

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran; 1,2-dimethoxyethane / Reflux

With 1,1'-bis-(diphenylphosphino)ferrocene; N-iodo-succinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium tert-butylate; potassium carbonate; acetic acid; trichlorophosphate; In tetrahydrofuran; 1,2-dimethoxyethane; chloroform; 1,2-dichloro-ethane; toluene;
DOI:10.1016/j.tet.2014.02.002