(E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine

Base Information

• Chemical Name: (E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine
• CAS No.: 1488023-38-6
• Molecular Formula: C₁₄H₁₃N
• Molecular Weight: 203.2
• Mol file: 1488023-38-6.mol

Synonyms:(E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine

Chemical Property of (E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine

There total 1 articles about (E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Acetophenone-methyl-d3 (17537-31-4) + aniline-d7 (14545-23-4) → (E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine (1488023-38-6) + (E)-N-pentadeuteriophenyl-N-(2-dideuterio-1-phenylethylidene)amine (1488024-21-0) + (E)-N-pentadeuteriophenyl-N-(2-deuterio-1-phenylethylidene)amine (1488024-24-3) + (E)-N-pentadeuteriophenyl-N-1-phenylethylideneamine (1488024-27-6)

Guidance literature:

In toluene; at 65 ℃; for 24h; Molecular sieve; Inert atmosphere;

DOI:10.1021/ja409344w

Reference yield:

Dimethylphenylsilane (766-77-8) + (E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine (1488023-38-6) → N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethyl)-N-[dimethyl(phenyl)]silylamine (1488023-34-2)

Guidance literature:

With (S)-4-(pentafluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]borepine tetrahydrofuran; In 1,2-dichloro-benzene; at 20 ℃; Reagent/catalyst;

DOI:10.1021/ja409344w

Reference yield:

N-(1-phenylethylidene)aniline (1749-19-5) + (E)-N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethylidene)amine (1488023-38-6) → C14H7(2)H8N (1488023-82-0) + C14H8(2)H7N (1488023-61-5) + C14H9(2)H6N (1488023-63-7) + C14H10(2)H5N (1488023-66-0) + C14H13(2)H2N (1488023-70-6) + 2-Deuterio-1-phenyl-N-phenylethylamine

Guidance literature:

With (S)-4-(pentafluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]borepine tetrahydrofuran; Dimethylphenylsilane; In 1,2-dichloro-benzene; at 20 ℃; for 72h; Reagent/catalyst; Glovebox; Inert atmosphere;

DOI:10.1021/ja409344w

upstream raw materials:

Acetophenone-methyl-d3

aniline-d₇

Downstream raw materials:

N-pentadeuteriophenyl-N-(2-trideuterio-1-phenylethyl)-N-[dimethyl(phenyl)]silylamine

C₁₄H₇⁽²⁾H₈N

C₁₄H₈⁽²⁾H₇N

C₁₄H₉⁽²⁾H₆N