(2S,3R)-2-((E)-3-(benzyloxy)prop-1-enyl)-3-(benzyloxymethyl)-1-tritylaziridine

Base Information

• Chemical Name: (2S,3R)-2-((E)-3-(benzyloxy)prop-1-enyl)-3-(benzyloxymethyl)-1-tritylaziridine
• CAS No.: 1254206-64-8
• Molecular Formula: C₃₉H₃₇NO₂
• Molecular Weight: 551.728
• Mol file: 1254206-64-8.mol

Synonyms:(2S,3R)-2-((E)-3-(benzyloxy)prop-1-enyl)-3-(benzyloxymethyl)-1-tritylaziridine

Chemical Property of (2S,3R)-2-((E)-3-(benzyloxy)prop-1-enyl)-3-(benzyloxymethyl)-1-tritylaziridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2S,3R)-2-((E)-3-(benzyloxy)prop-1-enyl)-3-(benzyloxymethyl)-1-tritylaziridine

There total 1 articles about (2S,3R)-2-((E)-3-(benzyloxy)prop-1-enyl)-3-(benzyloxymethyl)-1-tritylaziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

deuteromethanol (1455-13-6) + (2S,3R)-2-(benzyloxymethyl)-3-(tributylstannyl)-1-tritylaziridine (1254206-54-6) → N-allylidene-1,1,1-triphenylmethanamine (1051925-19-9) + (E)-((3-methoxyallyloxy)methyl)benzene (1254206-62-6) + N-(3-(benzyloxy)propylidene)-1,1,1-triphenylmethanamine (1254206-59-1) + (3R)-2-(benzyloxymethyl)-1-tritylaziridine-3-d1 + (2S,3R)-2-((E)-3-(benzyloxy)prop-1-enyl)-3-(benzyloxymethyl)-1-tritylaziridine (1254206-64-8)

Guidance literature:

(2S,3R)-2-(benzyloxymethyl)-3-(tributylstannyl)-1-tritylaziridine; With n-butyllithium; In tetrahydrofuran; hexanes; at -60 - -20 ℃; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; hexanes; at -78 - 20 ℃; Inert atmosphere;

deuteromethanol; With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri tert-butylphosphoniumtetrafluoroborate; In tetrahydrofuran; hexanes; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ol101904a

upstream raw materials:

deuteromethanol

(2S,3R)-2-(benzyloxymethyl)-3-(tributylstannyl)-1-tritylaziridine