1051925-19-9

Upstream product

• 5824-40-8 Triphenylmethylamin 
• 107-02-8 acrolein 
• 848129-49-7 N-tritylprop-2-yn-1-amine 
• 1455-13-6 deuteromethanol 
• 1254206-54-6 (2S,3R)-2-(benzyloxymethyl)-3-(tributylstannyl)-1-tritylaziridine 

Downstream Products

• 1051925-33-7 propyl 5-cyano-2,2-dimethyl-5-(tritylamino)pentanoate 
• 1051925-44-0 S-isopropyl 5-cyano-2-methyl-5-(tritylamino)pentanethioate 
• 1051925-46-2 S-propyl 5-cyano-2-methyl-5-(tritylamino)pentanethioate 
• 1051925-29-1 methyl 1-(3-amino-3-cyanopropyl)cyclohexanecarboxylate 
• 1051925-31-5 ethyl 5-cyano-2,2-dimethyl-5-(tritylamino)pentanoate 
• 1051925-47-3 S-ethyl 5-cyano-2,2-dimethyl-5-(tritylamino)pentanethioate 
• 1051925-42-8 S-ethyl 5-cyano-2-methyl-5-(tritylamino)pentanethioate 
• 1051925-34-8 isopropyl 5-cyano-2,2-dimethyl-5-(tritylamino)pentanoate 
• 1051925-43-9 S-tert-butyl 5-cyano-2-methyl-5-(tritylamino)pentanethioate 
• 1051925-45-1 S-phenyl 5-cyano-2-methyl-5-(tritylamino)pentanethioate 
• 1051925-36-0 ethyl 5-cyano-2,2-diethoxy-5-(tritylamino)pentanoate 
• 1051925-38-2 tert-butyl 5-cyano-2,2-dimethyl-5-(tritylamino)pentanoate 
• 1338366-81-6 C₂₉H₃₅NO₂ 
• 1338366-92-9 C₃₀H₃₅NOS 

Relevant academic research and scientific papers

Metalated aziridines for cross-coupling with aryl and alkenyl halides via palladium catalysis

The palladium-catalyzed coupling of an aziridinylzinc chloride intermediate with alkenyl and aryl halides has been demonstrated. The method provides products with retention of aziridine stereochemistry. The utility of the coupling procedure is illustrated

N-allylideneamines derived from acrolein: synthesis and use as acceptors of two nucleophiles

Two practical methods have been developed for the preparation of N-allylideneamines 1b,c. One involves the isomerlzation of propargylamines and the other the dehydration of acrolein. N-Allylideneamines 1b,c thus prepared, were used as efficient substrates

Conjugated imines and iminium salts as versatile acceptors of nucleophiles

Growing interests in nitrogen-containing molecules involving bioactive and functional materials have stimulated the recent development of synthetic methodologies where nucleophilic addition reactions to imino carbons are utilized in crucial steps. This article summarizes double nucleophilic addition reactions with α,β-unsaturated aldimines, addition reactions using alkynyl imines, "umpoled" reactions of α-imino esters, and the use of iminium salts as reactive electrophiles. The Royal Society of Chemistry 2009.

Synthesis of N-allylideneamines and their use for the double nucleophilic addition of ketene silyl (thio)acetals and trimethylsilyl cyanide

(Chemical Equation Presented) N-Allylideneamines 1a,b were prepared from acrolein and diphenylethyl or trityl amine in the presence of Ti(OEt) 4. Double nucleophilic addition of various ketene silyl (thio)acetals and trimethylsilyl cyanide to t