9,10-Diazapentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decan-9,10-dicarbonsaeure-diphenylester

Base Information

• Chemical Name: 9,10-Diazapentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decan-9,10-dicarbonsaeure-diphenylester
• CAS No.: 81226-17-7
• Molecular Formula: C₂₂H₁₈N₂O₄
• Molecular Weight: 374.396
• Mol file: 81226-17-7.mol

Synonyms:9,10-Diazapentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decan-9,10-dicarbonsaeure-diphenylester

Chemical Property of 9,10-Diazapentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decan-9,10-dicarbonsaeure-diphenylester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9,10-Diazapentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decan-9,10-dicarbonsaeure-diphenylester

There total 4 articles about 9,10-Diazapentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decan-9,10-dicarbonsaeure-diphenylester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

7,8-Diazatricyclo<4.2.2.02,5>deca-3,9-dien-7,8-dicarbonsaeure-diphenylester (81226-15-5,142433-81-6) → 9,10-Diazapentacyclo<4.4.0.02,5.03,8.04,7>decan-9,10-dicarbonsaeure-diphenylester (81226-17-7)

Guidance literature:

In acetone; for 12h; Irradiation;

Reference yield:

7,8-Dibromobicyclo<4.2.0>octa-2,4-diene (27587-70-8) → 9,10-Diazapentacyclo<4.4.0.02,5.03,8.04,7>decan-9,10-dicarbonsaeure-diphenylester (81226-17-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 63 percent / benzene / 3 h / 80 °C

2: 48 percent / Li/Hg / tetrahydrofuran / 16 h

3: 48 percent / acetone / 12 h / Irradiation

With lithium amalgam; In tetrahydrofuran; acetone; benzene;

Reference yield:

trans-3,4-Dibrom-7,8-diazatricyclo<4.2.2.02,5>dec-9-en-7,8-dicarbonsaeure-diphenylester (81226-14-4) → 9,10-Diazapentacyclo<4.4.0.02,5.03,8.04,7>decan-9,10-dicarbonsaeure-diphenylester (81226-17-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 48 percent / Li/Hg / tetrahydrofuran / 16 h

2: 48 percent / acetone / 12 h / Irradiation

With lithium amalgam; In tetrahydrofuran; acetone;

upstream raw materials:

7,8-Diazatricyclo<4.2.2.0^2,5>deca-3,9-dien-7,8-dicarbonsaeure-diphenylester

7,8-Dibromobicyclo<4.2.0>octa-2,4-diene

trans-3,4-Dibrom-7,8-diazatricyclo<4.2.2.0^2,5>dec-9-en-7,8-dicarbonsaeure-diphenylester

Diphenyl azodicarboxylate

Downstream raw materials:

(+/-)-4,5-Diazatricyclo<4.4.0.0^3,8>decan-4,5-dicarbonsaeure-diphenylester

(+)-(1R,3R,6R,8R)-4,5-Diazatricyclo<4.4.0.0^3,8>decan-4,5-dicarbonsaeure-diphenylester

(-)-(1S,3S,6S,8S)-4,5-Diazatricyclo<4.4.0.0^3,8>decan-4,5-dicarbonsaeure-diphenylester

9,10-Diazapentacyclo<4.4.0.0^2,4.0^3,8.0^5,7>decan-9,10-dicarbonsaeurediphenylester