tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate

Base Information

Chemical Name:tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate
CAS No.:211386-13-9
Molecular Formula:C₂₁H₃₄O₃SSi
Molecular Weight:394.651
Hs Code.:

Synonyms:tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate

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Technology Process of tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate

There total 2 articles about tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 540-88-5
acetic acid tert-butyl ester

: 152452-56-7
(E)-1-(tert-Butyl-dimethyl-silanyl)-3-phenylsulfanyl-propenone

: 211386-13-9
tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate

Guidance literature:: acetic acid tert-butyl ester; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -80 ℃; for 30h;

(E)-1-(tert-Butyl-dimethyl-silanyl)-3-phenylsulfanyl-propenone; In tetrahydrofuran; hexane; Further stages.;
DOI:10.1021/jo0160219

Reference yield: 31.0%

: 1207973-75-8
lithium tert-butyl acetate

: 152452-56-7
(E)-1-(tert-Butyl-dimethyl-silanyl)-3-phenylsulfanyl-propenone

: 211386-13-9
tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate

: (E)-3-(tert-Butyl-dimethyl-silanyloxy)-5-phenylsulfanyl-pent-3-enoic acid tert-butyl ester

Guidance literature:: In tetrahydrofuran; at -85 ℃; for 0.5h;
DOI:10.1016/S0040-4039(98)01032-6

Reference yield:

: 211386-13-9
tert-bytyl (E)-3-tert-butyl(dimethyl)silyl-3-hydroxy-5-phenylthio-4-pentenoate

: 3-(tert-butyl-dimethyl-silanyloxy)-5-phenylsulfanyl-pent-3-enoic acid tert-butyl ester

: 3-(tert-butyl-dimethyl-silanyloxy)-5-phenylsulfanyl-pent-3-enoic acid tert-butyl ester

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dimethylsulfoxide-d6; at 23 ℃; Title compound not separated from byproducts.;
DOI:10.1021/jo0160219