2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide

Base Information

• Chemical Name: 2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide
• CAS No.: 1456728-87-2
• Molecular Formula: C₂₁H₁₈N₂O₂
• Molecular Weight: 330.386
• Mol file: 1456728-87-2.mol

Synonyms:2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide

Chemical Property of 2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide

There total 3 articles about 2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

benzaldehyde (100-52-7) + 1,2-bis(4-methylphenyl)diazene oxide (955-98-6,21650-69-1,71297-92-2) → 2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide (1456728-87-2)

Guidance literature:

With tert.-butylhydroperoxide; palladium(II) trifluoroacetate; In 1,2-dichloro-ethane; at 60 ℃; for 24h; regioselective reaction; Inert atmosphere;

DOI:10.1002/adsc.201400594

Reference yield: 68.0%

Benzoylformic acid (611-73-4) + 1,2-bis(4-methylphenyl)diazene oxide (955-98-6,21650-69-1,71297-92-2) → 2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide (1456728-87-2)

Guidance literature:

With dipotassium peroxodisulfate; palladium diacetate; In 1,2-dichloro-ethane; at 60 ℃; for 24h; regioselective reaction; Sealed tube;

DOI:10.1039/c3cc45492d

Reference yield: 60.0%

1,2-bis(4-methylphenyl)diazene oxide (955-98-6,21650-69-1,71297-92-2) + benzyl alcohol (100-51-6,185532-71-2) → 2-(2-benzoyl-4-methylphenyl)-2-oxo-1-(p-tolyl)hydrazin-2-ium-1-ide (1456728-87-2)

Guidance literature:

With tert.-butylhydroperoxide; palladium(II) trifluoroacetate; In 1,2-dichloro-ethane; at 100 ℃; for 20h; regioselective reaction; Sealed tube;

DOI:10.1039/c5ob00089k

upstream raw materials:

Benzoylformic acid

1,2-bis(4-methylphenyl)diazene oxide

benzaldehyde

benzyl alcohol