C₂₇H₄₇NO₄Si

Base Information

Chemical Name:C₂₇H₄₇NO₄Si
CAS No.:1417601-00-3
Molecular Formula:C₂₇H₄₇NO₄Si
Molecular Weight:477.76
Hs Code.:

C<sub>27</sub>H<sub>47</sub>NO<sub>4</sub>Si

Synonyms:C₂₇H₄₇NO₄Si

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Chemical Property of C₂₇H₄₇NO₄Si

Chemical Property:

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Technology Process of C₂₇H₄₇NO₄Si

There total 14 articles about C₂₇H₄₇NO₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 2-((1S,2R,3S,Z)-2-((tert-butyldimethylsilyl)oxy)-3-methyl-5-oxo-6-(pyrrolidin-2-ylidene)cyclohexyl)ethyl pivalate

: 762-72-1
allyl-trimethyl-silane

: 1417601-00-3
C₂₇H₄₇NO₄Si

: 1417600-72-6
2-((1S,2S,5S,6S)-2-allyl-6-((tert-butyldimethylsilyl)oxy)-2-(3,4-dihydro-2H-pyrrol-5-yl)-5-methyl-3-oxocyclohexyl)ethyl pivalate

Guidance literature:: With ammonium cerium (IV) nitrate; In acetonitrile; at 0 ℃; for 0.166667h; Inert atmosphere;
DOI:10.1021/jo302333s

Reference yield:

: 1131783-50-0
(4S,5S,E)-ethyl 4-((tert-butyldimethylsilyl)oxy)-7-hydroxy-5-methylhept-2-enoate

: 1417601-00-3
C₂₇H₄₇NO₄Si

: 1417600-72-6
2-((1S,2S,5S,6S)-2-allyl-6-((tert-butyldimethylsilyl)oxy)-2-(3,4-dihydro-2H-pyrrol-5-yl)-5-methyl-3-oxocyclohexyl)ethyl pivalate

Guidance literature:: Multi-step reaction with 7 steps

1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C / Inert atmosphere

2: sodium chlorite; 2-methyl-but-2-ene; sodium dihydrogen phosphate monohydrate / water; acetonitrile; tert-butyl alcohol / 3.5 h / 0 °C / Inert atmosphere

3: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane

4: ammonium cerium (IV) nitrate / water; acetonitrile / 0.08 h / 20 °C / Inert atmosphere

5: sodium bis(2-methoxyethoxy)aluminium dihydride / toluene / 1 h / 0 - 20 °C / Inert atmosphere

6: dmap; triethylamine / dichloromethane / 40 h / 20 °C / Inert atmosphere

7: ammonium cerium (IV) nitrate / acetonitrile / 0.17 h / 0 °C / Inert atmosphere

With dmap; sodium chlorite; ammonium cerium (IV) nitrate; sodium dihydrogen phosphate monohydrate; 2-methyl-but-2-ene; oxalyl dichloride; Dess-Martin periodane; triethylamine; N,N-dimethyl-formamide; sodium bis(2-methoxyethoxy)aluminium dihydride; In dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol; 4: |Michael Addition;
DOI:10.1021/jo302333s

Reference yield:

: 6097-07-0
N-(pent-4-ynyl)phthalimide

: 1417601-00-3
C₂₇H₄₇NO₄Si

: 1417600-72-6
2-((1S,2S,5S,6S)-2-allyl-6-((tert-butyldimethylsilyl)oxy)-2-(3,4-dihydro-2H-pyrrol-5-yl)-5-methyl-3-oxocyclohexyl)ethyl pivalate

Guidance literature:: Multi-step reaction with 8 steps

1: hydrazine / methanol

2: benzene / 72 h / 20 °C / Inert atmosphere; Molecular sieve

3: 2,2'-azobis(isobutyronitrile) / benzine / 85 °C

4: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane

5: ammonium cerium (IV) nitrate / water; acetonitrile / 0.08 h / 20 °C / Inert atmosphere

6: sodium bis(2-methoxyethoxy)aluminium dihydride / toluene / 1 h / 0 - 20 °C / Inert atmosphere

7: dmap; triethylamine / dichloromethane / 40 h / 20 °C / Inert atmosphere

8: ammonium cerium (IV) nitrate / acetonitrile / 0.17 h / 0 °C / Inert atmosphere

With dmap; ammonium cerium (IV) nitrate; oxalyl dichloride; 2,2'-azobis(isobutyronitrile); triethylamine; N,N-dimethyl-formamide; sodium bis(2-methoxyethoxy)aluminium dihydride; hydrazine; In methanol; benzine; dichloromethane; water; toluene; acetonitrile; benzene; 1: |Gabriel Amine Synthesis / 5: |Michael Addition;
DOI:10.1021/jo302333s