tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd

Base Information

• Chemical Name: tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd
• CAS No.: 1421017-07-3
• Molecular Formula: C₇₁H₆₂N₆O₆P₂
• Molecular Weight: 1157.26
• Mol file: 1421017-07-3.mol

Synonyms:tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd

Chemical Property of tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd

There total 4 articles about tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

4-{N,N-bis[4-(N,N-diphenylamino)phenyl]amino}benzaldehyde (943784-68-7) + hexamethyl (((1,3,5-triazine-2,4,6-triyl)tris(benzene-4,1-3-diyl))tris(methylene))tris(phosphonate) (1198174-23-0) → tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd (1421017-07-3)

Guidance literature:

With 18-crown-6 ether; potassium tert-butylate; In dichloromethane; at 45 ℃; for 6h; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.11.131

Reference yield:

2,4,6-tris(p-tolyl)-1,3,5-triazine (6726-45-0) → tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd (1421017-07-3)

Guidance literature:

Multi-step reaction with 3 steps

1: N-Bromosuccinimide; dibenzoyl peroxide / chlorobenzene / 7 h / 110 °C

2: chlorobenzene / 9 h / Reflux

3: 18-crown-6 ether; potassium tert-butylate / dichloromethane / 6 h / 45 °C / Inert atmosphere

With N-Bromosuccinimide; 18-crown-6 ether; potassium tert-butylate; dibenzoyl peroxide; In dichloromethane; chlorobenzene; 3: |Wittig-Horner Reaction;

DOI:10.1016/j.tetlet.2012.11.131

Reference yield:

4-(diphenylamino)benzaldehyde (4181-05-9) → tetramethyl (((6-(4-(4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(methylene))bis(phosphonate)nd (1421017-07-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium iodide / water; acetic acid / 1 h / 80 °C

1.2: 4 h / 80 °C

2.1: potassium carbonate; 18-crown-6 ether / 1,2-dichloro-benzene / 48 °C / Inert atmosphere; Reflux

3.1: 18-crown-6 ether; potassium tert-butylate / dichloromethane / 6 h / 45 °C / Inert atmosphere

With 18-crown-6 ether; potassium tert-butylate; potassium carbonate; potassium iodide; In dichloromethane; water; acetic acid; 1,2-dichloro-benzene; 2.1: |Ullmann Condensation / 3.1: |Wittig-Horner Reaction;

DOI:10.1016/j.tetlet.2012.11.131

upstream raw materials:

2,4,6-tris(p-tolyl)-1,3,5-triazine

4-{N,N-bis[4-(N,N-diphenylamino)phenyl]amino}benzaldehyde

hexamethyl (((1,3,5-triazine-2,4,6-triyl)tris(benzene-4,1-3-diyl))tris(methylene))tris(phosphonate)

4-(diphenylamino)benzaldehyde

Downstream raw materials:

1,1'-(((((1E,1'E)-((6-(4-((E)-4-(bis(4-(diphenylamino)phenyl)amino)styryl)phenyl)-1,3,5-triazine-2,4-diyl)bis(4,1-phenylene))bis(ethene-2,1-diyl))bis(4,1-phenylene))bis(oxy))bis(hexane-6,1-diyl))bis(5-methylpyrimidine-2,4(1H,3H)-dione)