Carbamic acid, (6-hydroxy-1-cyclohexen-1-yl)-, methyl ester (9CI)

Base Information

Chemical Name:Carbamic acid, (6-hydroxy-1-cyclohexen-1-yl)-, methyl ester (9CI)
CAS No.:881851-63-4
Molecular Formula:C₈H₁₃NO₃
Molecular Weight:171.196
Hs Code.:
Mol file:881851-63-4.mol

Synonyms:Carbamic acid, (6-hydroxy-1-cyclohexen-1-yl)-, methyl ester (9CI)

Suppliers and Price of Carbamic acid, (6-hydroxy-1-cyclohexen-1-yl)-, methyl ester (9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Carbamic acid, (6-hydroxy-1-cyclohexen-1-yl)-, methyl ester (9CI)

Chemical Property:

PSA：58.56000
LogP:1.16200

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Carbamic acid, (6-hydroxy-1-cyclohexen-1-yl)-, methyl ester (9CI)

There total 5 articles about Carbamic acid, (6-hydroxy-1-cyclohexen-1-yl)-, methyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 172686-91-8
2-(methoxycarbonylamino)-cyclohex-2-en-1-one

: 881851-63-4
(R)-(+)-2-(methoxycarbonylamino)-cyclohex-2-en-1-ol

Guidance literature:: With formic acid; (R,R)-1,2-diphenylethylenediamine monotosylate; triethylamine; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; at 28 ℃;
DOI:10.1055/s-2002-19747

Reference yield: 26.0%

: 172686-91-8
2-(methoxycarbonylamino)-cyclohex-2-en-1-one

: 881851-63-4
(R)-(+)-2-(methoxycarbonylamino)-cyclohex-2-en-1-ol

: (+/-)-2-(methoxycarbonylamino)-cyclohexan-1-one

: (2-hydroxy-cyclohexyl)-carbamic acid methyl ester

: trans-(2-hydroxy-cyclohexyl)-carbamic acid methyl ester

Guidance literature:: With formic acid; (R,R)-1,2-diphenylethylenediamine monotosylate; triethylamine; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; at 20 ℃; for 216h; Further byproducts given;
DOI:10.1055/s-2002-19747

Reference yield:

: 80522-46-9
1-triisopropylsiloxy-1-cyclohexene

: 881851-63-4
(R)-(+)-2-(methoxycarbonylamino)-cyclohex-2-en-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 68 percent / sodium azide; (NH₄)2Ce(NO₃)6 / acetonitrile / 1.5 h / -20 °C

2: 38 percent / trifluoroacetic acid; sodium perrhenate / 6 h / 55 °C

3: 54 percent / formic acid; triethylamine; (R,R)-(-)-N-(p-toluenesulfonyl)-1,2-diphenylethylene-diamine / (p-cymene) ruthenium(II) chloride dimer / 28 °C

With formic acid; sodium azide; sodium perrhenate; ammonium cerium(IV) nitrate; 4-methyl-N-((1R,2R)-2-{[(4-methylphenyl)sulfonyl]amino}-1,2-diphenylethyl)benzenesulfonamide; triethylamine; trifluoroacetic acid; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; In acetonitrile;
DOI:10.1016/j.tet.2005.11.036