N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide

Base Information

• Chemical Name: N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide
• CAS No.: 358762-72-8
• Molecular Formula: C₅₀H₅₁BrN₂O₄
• Molecular Weight: 823.87
• Mol file: 358762-72-8.mol

Synonyms:N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide

Chemical Property of N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide

There total 3 articles about N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

N-(2,5-di-tert-butyl-phenyl)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide (358762-71-7) → N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide (358762-72-8)

Guidance literature:

N-(2,5-di-tert-butyl-phenyl)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide; With potassium hydroxide; In tert-butyl alcohol; for 3h; Heating;

With hydrazine; In ethanol; at 20 ℃; for 18h; Further stages.;

DOI:10.1021/jp011561v

Reference yield:

N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide (165261-25-6) → N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide (358762-72-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 65 percent / Bromine / CHCl₃ / 2.5 h / Heating

2.1: 55 percent / CsCO₃; CuI / ethyl acetate; toluene / 6 h / Heating

3.1: KOH / 2-methyl-propan-2-ol / 3 h / Heating

3.2: 20 percent / NH₂NH₂ / ethanol / 18 h / 20 °C

With potassium hydroxide; copper(l) iodide; bromine; In chloroform; ethyl acetate; toluene; tert-butyl alcohol;

DOI:10.1021/jp011561v

Reference yield:

N-(2,5-di-tert-butyl-phenyl)-1,6,9-tribromoperylene-3,4-dicarboximide (358762-70-6) → N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide (358762-72-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 55 percent / CsCO₃; CuI / ethyl acetate; toluene / 6 h / Heating

2.1: KOH / 2-methyl-propan-2-ol / 3 h / Heating

2.2: 20 percent / NH₂NH₂ / ethanol / 18 h / 20 °C

With potassium hydroxide; copper(l) iodide; In ethyl acetate; toluene; tert-butyl alcohol;

DOI:10.1021/jp011561v

upstream raw materials:

N-(2,5-di-tert-butyl-phenyl)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide

N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

N-(2,5-di-tert-butyl-phenyl)-1,6,9-tribromoperylene-3,4-dicarboximide

Downstream raw materials:

N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-(N-pyrrolidinyl)perylene-3,4-dicarboximide