358762-70-6

Upstream product

• 128-69-8 perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride 
• 21860-03-7 2,5-di-tert-butylaniline 
• 165261-25-6 N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide 

Downstream Products

• 1307916-84-2 N-(carboxymethyl)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide 
• 1307916-82-0 N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide 
• 1307916-81-9 1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboxylic anhydride 
• 1307916-80-8 1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)-N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide 
• 572901-51-0 N-(2,5-di-tert-butylphenyl)-1,6,9-tricyano-perylene-3,4-dicarboximide 
• 358762-73-9 N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-(N-pyrrolidinyl)perylene-3,4-dicarboximide 
• 358762-72-8 N-(amino)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide 
• 358762-71-7 N-(2,5-di-tert-butyl-phenyl)-1,6-bis-(3,5-di-tert-butylphenoxy)-9-bromoperylene-3,4-dicarboximide 
• 524960-76-7 1,6,9-tris(4-tert-butylphenoxy)-N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide 

Relevant academic research and scientific papers

Solvatochromic rotaxane molecular shuttles

A strongly fluorescent bistable rotaxane is described in which the relative position of the macrocyclic ring with respect to a solvatochromic fluorophore gives a strong response in the spectral domain.

Practical synthesis of perylene-monoimide building blocks that possess features appropriate for use in porphyrin-based light-harvesting arrays

Perylene-monoimide dyes with solubilizing aryloxy substituents at the perylene perimeter and a synthetic handle on the N-aryl group are valuable building blocks for incorporation as accessory pigments in porphyrin-based light-harvesting arrays. A family of such dyes has been prepared by reaction of 1,6,9-tris(4-tert-butylphenoxy)perylene-3,4-dicarboxylic anhydride with a set of 4-iodo/ethynyl anilines (with or without 2,6-diisopropyl substituents) in the presence of Zn(OAc)2·2H2O in imidazole/mesitylene at 130°C. The workup procedures throughout the synthesis have been streamlined for scale-up purposes, minimizing chromatography. Two bis(perylene)porphyrin building blocks were prepared in a rational manner and examined in Sonogashira and Glaser polymerizations. The two isopropyl groups on the N-aryl group and the three 4-tert-butylphenoxy groups at the perylene perimeter are essential for high solubility of the bis(perylene)porphyrins and corresponding oligomers in organic solvents.

SYNTHESIS OF PERYLENE-PORPHYRIN BUILDING BLOCKS AND POLYMERS THEREOF FOR THE PRODUCTION OF LIGHT-HARVESTING ARRAYS

The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula (I): wherein m is at least 1; X1 is a charge separation group, and X2 through Xm+1 are chromophores. At least one of X2 through Xm+1 has at least one perylene group coupled thereto.

Photorefractivity in nematic liquid crystals using a donor-acceptor dyad with a low-lying excited singlet state for charge generation

The photorefractive effect was observed in room-temperature nematic liquid crystal composites consisting of a eutectic mixture of 65% 4a?2-(n-pentyl)-4-cyanobiphenyl and 35% 4a?2-(n-octyloxy)-4-cyanobiphenyl doped with a donor-acceptor dyad in which 9-(N-