benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate

Base Information

Chemical Name:benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate
CAS No.:940868-32-6
Molecular Formula:C₁₅H₁₉N₃O₃
Molecular Weight:289.334
Hs Code.:

Synonyms:benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate

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Chemical Property of benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate

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Technology Process of benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate

There total 3 articles about benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 519031-96-0
benzyl 1-cyano-7-azabicyclo[2.2.1]heptane-7-carboxylate

: 940868-32-6
benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate

Guidance literature:: With hydroxylamine; In methanol; at 60 ℃;
DOI:10.1021/jm070027u

Reference yield:

: 519031-95-9
1-carbamoyl-7-aza-bicyclo[2.2.1]heptane-7-carboxylic acid benzyl ester

: 940868-32-6
benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: Et₃N; trifluoroacetic anhydride / CH₂Cl₂ / 3.5 h / 20 °C

2: NH₂OH / methanol / 60 °C

With hydroxylamine; triethylamine; trifluoroacetic anhydride; In methanol; dichloromethane;
DOI:10.1021/jm070027u

Reference yield:

: 182137-60-6
7-[(benzyloxy)carbonyl]-7-azabicyclo[2.2.1]heptane-1-carboxylic acid

: 940868-32-6
benzyl 1-[amino(hydroxyimino)methyl]-7-azabicyclo[2.2.1]heptane-7-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: di-tert-butyl dicarbonate; NH₄HCO₃; pyridine / dioxane / 20 h / 20 °C

2: Et₃N; trifluoroacetic anhydride / CH₂Cl₂ / 3.5 h / 20 °C

3: NH₂OH / methanol / 60 °C

With pyridine; di-tert-butyl dicarbonate; hydroxylamine; ammonium bicarbonate; triethylamine; trifluoroacetic anhydride; In 1,4-dioxane; methanol; dichloromethane;
DOI:10.1021/jm070027u