N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide

Base Information

Chemical Name:N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide
CAS No.:851539-74-7
Molecular Formula:C₂₉H₂₇IN₂Pd
Molecular Weight:636.871
Hs Code.:

Synonyms:N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide

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Chemical Property of N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide

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Technology Process of N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide

There total 1 articles about N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 185406-04-6
N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl chloride

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 851539-74-7
N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide

Guidance literature:: In dichloromethane; acetone; (Ar), mixed in dry box, treated with CH2Cl2 and acetone, stirred for several min; evapd.(vac.), treated with dry CH2Cl2, filtered, concd.(vac.), pptd.(CH3OH), evapd.(vac.), elem. anal.;
DOI:10.1021/ja045969s

Reference yield: 77.0%

: 26042-64-8
silver hexafluoroantimonate

: 851539-74-7
N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide

: 851539-75-8
N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)(diethyl ether) hexafluoroantimonate

Guidance literature:: In diethyl ether; dichloromethane; byproducts: AgI; (Ar), Pd complex and AgSbF6 cooled to -78°C, slowly treated with CH2Cl2 and ether; filtered at -78°C, treated with ether, evapd.(vac.) at -10°C, ether added, filtered, concd.(vac.), solid dried (vac.) at -40°C for 2 h;
DOI:10.1021/ja045969s

Reference yield:

: 26042-64-8
silver hexafluoroantimonate

: 108-05-4,9003-20-7
vinyl acetate

: 851539-74-7
N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl iodide

: 851539-82-7
N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)(η2-vinyl acetate) hexafluoroantimonate

Guidance literature:: In dichloromethane-d2; (Ar), in NMR tube, Pd complex and AgSbF6 cooled to -78°C, slowly treated with CD2Cl2 and vinyl acetate, vivorously shaked; not isolated, detected by NMR; Kinetics;
DOI:10.1021/ja045969s