cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

Base Information

Chemical Name:cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one
CAS No.:87372-39-2
Molecular Formula:C₃₂H₃₂N₂O₄S₂
Molecular Weight:572.749
Hs Code.:

Synonyms:cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

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Chemical Property of cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

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Technology Process of cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

There total 3 articles about cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 87393-13-3
cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-thione

: 87372-39-2
cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

Guidance literature:: With triethyloxonium fluoroborate; In dichloromethane; 10 min, 0 deg C then 1 h, 25 deg C;
DOI:10.1021/ja00262a005

Reference yield:

: 87372-37-0
cis-4a-ethyl-1,3,4,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-thione

: 87372-39-2
cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / p-toluenesulfinyl chloride, i-Pr₂NEt / CH₂Cl₂ / 6 h / 20 °C

2: 57 percent / Et₃O(+)*BF₄(-) / CH₂Cl₂ / 10 min, 0 deg C then 1 h, 25 deg C

With 4-methylbenzenesulfinyl chloride; triethyloxonium fluoroborate; N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1021/ja00262a005

Reference yield:

: 80664-29-5
cis-4a-ethyl-1,3,4,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

: 87372-39-2
cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 62 percent / Lawesson reagent / toluene / 2 h / 90 °C

2: 82 percent / p-toluenesulfinyl chloride, i-Pr₂NEt / CH₂Cl₂ / 6 h / 20 °C

3: 57 percent / Et₃O(+)*BF₄(-) / CH₂Cl₂ / 10 min, 0 deg C then 1 h, 25 deg C

With Lawessons reagent; 4-methylbenzenesulfinyl chloride; triethyloxonium fluoroborate; N-ethyl-N,N-diisopropylamine; In dichloromethane; toluene;
DOI:10.1021/ja00262a005