phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside

Base Information

• Chemical Name: phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside
• CAS No.: 1004554-59-9
• Molecular Formula: C₁₈H₂₆O₇S
• Molecular Weight: 386.466

Synonyms:phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside

Chemical Property of phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside

There total 2 articles about phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester (13992-16-0) → phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside (1004554-59-9)

Guidance literature:

Multi-step reaction with 2 steps

1: NaOH / methanol / 20 °C

2: (MeO)3CH; CSA / methanol / Heating

With sodium hydroxide; camphor-10-sulfonic acid; trimethyl orthoformate; In methanol;

DOI:10.1021/ol048525+

Reference yield:

phenyl-1-thio-α-D-glucopyranoside (13992-15-9) + 2,2,3,3-tetramethoxybutane (176798-33-7) → phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside (1004554-59-9)

Guidance literature:

With camphor-10-sulfonic acid; trimethyl orthoformate; In methanol; Heating;

DOI:10.1021/ol048525+

Reference yield:

benzyl bromide (100-39-0) + phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside (1004554-59-9) → (2S,3S,4aR,5R,7R,8R,8aS)-8-Benzyloxy-5-benzyloxymethyl-2,3-dimethoxy-2,3-dimethyl-7-phenylsulfanyl-hexahydro-pyrano[3,4-b][1,4]dioxine

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1021/ol048525+

upstream raw materials:

phenyl-1-thio-α-D-glucopyranoside

2,2,3,3-tetramethoxybutane

Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester

Downstream raw materials:

(2'S,3'S)-2,6-Di-O-benzyl-3,4-di-O-(2',3'-dimethoxybutane-2',3'-diyl)-D-glucono-1,5-lactone

(2S,3S,4aR,5R,7S,8S,8aR)-7-Allyl-8-benzyloxy-5-benzyloxymethyl-2,3-dimethoxy-2,3-dimethyl-hexahydro-pyrano[3,4-b][1,4]dioxine

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1004554-59-9 phenyl 3,4-O-[(2S,3R)-2,3-dimethoxybutane-2,3-diyl]-1-thio-α-D-glucopyranoside

Send

Send

Metric Ton KG G Pound L ML

Send

Send