1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol

Base Information

Chemical Name:1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol
CAS No.:104976-40-1
Molecular Formula:C₄₄H₄₈O₅Si
Molecular Weight:684.948
Hs Code.:

Synonyms:1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol

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Chemical Property of 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol

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Technology Process of 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol

There total 3 articles about 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 104976-75-2
2D-(2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-2,3,4-trihydroxy-5-cyclohexen-1-on

: 104976-40-1
1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol

: 105017-71-8
1L-(1,3/2,4)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol

Guidance literature:: With sodium tetrahydroborate; In ethanol; for 12h; Ambient temperature;

Reference yield:

: 104976-74-1,104976-79-6
[(3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-2,6-dihydroxy-heptyl]-phosphonic acid dimethyl ester

: 104976-40-1
1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) (COCl)2, DMSO; 2.) NEt(iPr)2 / 1.) CH₂Cl₂, 2 h, -78 deg C; 2.) CH₂Cl₂₁₂ h, room temp.

2: 35 percent / NaBH₄ / ethanol / 12 h / Ambient temperature

With sodium tetrahydroborate; oxalyl dichloride; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; In ethanol;

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 104976-40-1
1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 0 °C

2: 1.) (COCl)2, DMSO; 2.) NEt(iPr)2 / 1.) CH₂Cl₂, 2 h, -78 deg C; 2.) CH₂Cl₂₁₂ h, room temp.

3: 35 percent / NaBH₄ / ethanol / 12 h / Ambient temperature

With 1H-imidazole; sodium tetrahydroborate; oxalyl dichloride; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; In ethanol; N,N-dimethyl-formamide;